1,2,4-Triazolium perfluorobutanesulfonate as an archetypal pure protic organic ionic plastic crystal electrolyte for all-solid-state fuel cells

2015 ◽  
Vol 8 (4) ◽  
pp. 1276-1291 ◽  
Author(s):  
Jiangshui Luo ◽  
Annemette H. Jensen ◽  
Neil R. Brooks ◽  
Jeroen Sniekers ◽  
Martin Knipper ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Solid State ◽  
Proton Conductors ◽  
Plastic Crystal ◽  
Plastic Crystals

Protic organic ionic plastic crystals (POIPCs) are shown to be novel anhydrous solid-state proton conductors for fuel cells.

scholarly journals A new approach to very high lithium salt content quasi-solid state electrolytes for lithium metal batteries using plastic crystals

2019 ◽  
Vol 7 (44) ◽  
pp. 25389-25398 ◽  
Author(s):  
Danah Al-Masri ◽  
Ruhamah Yunis ◽  
Haijin Zhu ◽  
Liyu Jin ◽  
Peter Bruce ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Salt ◽  
Salt Content ◽  
Plastic Crystal ◽  
Lithium Metal ◽  
High Concentration ◽  
New Approach ◽  
Plastic Crystals ◽  
Lithium Metal Batteries ◽  
Very High

The combination of a highly conductivity plastic crystal with a very high concentration of lithium salt results in a promising new “plastic crystal in salt” electrolyte for lithium metal batteries.

Effect of secondary phase on thermal behaviour and solid-state ion conduction in lithium doped N-ethyl-N-methylpyrrolidinium tetrafluoroborate organic ionic plastic crystal

2017 ◽  
Vol 5 (47) ◽  
pp. 24909-24919 ◽  
Author(s):  
N. Iranipour ◽  
D. J. Gunzelmann ◽  
A. J. Seeber ◽  
J. Vongsvivut ◽  
A. F. Hollenkamp ◽  
...  
Keyword(s):  
Solid State ◽  
Crystalline Structure ◽  
Thermal Behaviour ◽  
Lithium Ion ◽  
Secondary Phase ◽  
Plastic Crystal ◽  
Ion Dynamics ◽  
Ion Conduction ◽  
Plastic Crystals

Microstructural features significantly affecting lithium ion dynamics and conduction within the crystalline structure of pyrrolidinium based organic ionic plastic crystals.

Heat Capacities of “Plastic Crystal” Solid State Thermal Energy Storage Materials

2002 ◽  
Vol 216 (12) ◽  
Author(s):  
D. Chandra ◽  
W.-M. Chien ◽  
V. Gandikotta ◽  
D. W. Lindle
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Heat Capacities ◽  
Energy Storage Materials ◽  
Plastic Crystal ◽  
Plastic Crystals ◽  
Storage Materials

The heat capacities of polyalcohol “Plastic Crystals,” such as pentaerythritol [PE, C–(CH

scholarly journals Predicting gas selectivity in organic ionic plastic crystals by free energy calculations

RSC Advances ◽  
2021 ◽  
Vol 11 (32) ◽  
pp. 19623-19629
Author(s):  
Vinay S. Kandagal ◽  
Jennifer M. Pringle ◽  
Maria Forsyth ◽  
Fangfang Chen
Keyword(s):  
Free Energy ◽  
Gas Separation ◽  
Free Energy Calculations ◽  
Free Energy Calculation ◽  
Energy Calculation ◽  
Plastic Crystal ◽  
Plastic Crystals ◽  
New Type ◽  
Gas Molecules ◽  
Gas Selectivity

The free energy calculation shows the different free energy changes of the adsorption and absorption of gas molecules into an organic ionic plastic crystal, successfully predicting the gas selectivity of this new type of gas separation material.

scholarly journals Solid-state proton conductors

1990 ◽  
Author(s):  
J.R. Jewulski ◽  
T.L. Osif ◽  
R.J. Remick
Keyword(s):  
Solid State ◽  
Proton Conductors

Solid-state mechanical alloying of plastic crystals

1997 ◽  
Vol 12 (12) ◽  
pp. 3254-3259 ◽  
Author(s):  
J. Font ◽  
J. Muntasell ◽  
E. Cesari ◽  
J. Pons
Keyword(s):  
Solid State ◽  
Binary System ◽  
Mechanical Alloying ◽  
Ball Milling ◽  
Room Temperature ◽  
Binary Systems ◽  
Solid Phase ◽  
Stable State ◽  
Plastic Crystals ◽  
Dsc Measurements

Ball milling has been used as a solid-state mechanical alloying technique in two binary systems of plastic crystals: neopentylglycol/pentaglycerin (NPG/PG), showing a partial solubility in the ordered phase, and 2-amino-2-methyl-1,3-propanediol/tris(hydroxymethyl) (AMP/TRIS) whose immiscibility in this ordered solid phase is almost total. For the AMP/TRIS system the stable state at room temperature was reached by milling. Contrarily, for NPG/PG, DSC measurements reveal that an annealing period is required after milling. These results have been compared with those of the pentaglycerin/pentaerythritol (PG/PE) binary system, previously studied, whose miscibility is total at room temperature.

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