A metal–metal bond passing through the arene ligand: a theoretical study on inverse sandwiches X[Sc–C8H8–Sc]nX (X = F, Cl, Br; n = 1, 2)

2015 ◽  
Vol 39 (3) ◽  
pp. 1558-1562 ◽  
Author(s):  
Nan-nan Liu ◽  
Yi-hong Ding

In X[Sc–C8H8–Sc]2X (X = F–Br), Sc–Sc bonds between two [Sc–C8H8–Sc] units and the Sc–Sc bond through C8H8 form the uninterrupted Sc–Sc–Sc–Sc bond-chain.

2019 ◽  
Vol 48 (1) ◽  
pp. 324-332 ◽  
Author(s):  
Luana-Flavia Radu ◽  
Amr A. A. Attia ◽  
Radu Silaghi-Dumitrescu ◽  
Alexandru Lupan ◽  
R. Bruce King

The addition of bases such as ammonia and trimethylphosphine to H2C2S2Mn2(CO)6 to give yellow 1 : 1 adducts is shown to break the metal–metal bond rather than displace the coordinated double bond.


1995 ◽  
Vol 229 (1-2) ◽  
pp. 469-471 ◽  
Author(s):  
N.J. Tro ◽  
J.C. King ◽  
C.B. Harris
Keyword(s):  

2011 ◽  
Vol 17 (37) ◽  
pp. 10230-10234 ◽  
Author(s):  
Tao Yang ◽  
Xiang Zhao ◽  
Eiji Osawa

1971 ◽  
Vol 31 (2) ◽  
pp. 227-232 ◽  
Author(s):  
H.C. Clark ◽  
B.K. Hunter
Keyword(s):  

1997 ◽  
Vol 16 (8) ◽  
pp. 1573-1580 ◽  
Author(s):  
Yu-Lee Yang ◽  
Luxti Jun-Jieh Wang ◽  
Ying-Chih Lin ◽  
Shou-Ling Huang ◽  
Ming-Chou Chen ◽  
...  
Keyword(s):  

1984 ◽  
Vol 23 (25) ◽  
pp. 4386-4388 ◽  
Author(s):  
Chi Ming Che ◽  
Thomas C. W. Mak ◽  
Harry B. Gray

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