Enantioselective synthesis of spiroacetals: the conquest of a long-sought goal in asymmetric catalysis

2014 ◽  
Vol 12 (29) ◽  
pp. 5324-5330 ◽  
Author(s):  
Lara Cala ◽  
Francisco J. Fañanás ◽  
Félix Rodríguez
Keyword(s):  
Asymmetric Synthesis ◽  
Asymmetric Catalysis ◽  
Enantioselective Synthesis ◽  
Catalytic Asymmetric Synthesis ◽  
Catalytic Asymmetric

This perspective article summarizes the few and recently reported methods on catalytic asymmetric synthesis of spiroacetal derivatives from achiral substrates.

Catalytic asymmetric synthesis of 1,3-enyne scaffolds: design and synthesis of conjugated nitro dienynes as novel Michael acceptors and development of a new synthetic methodology

2014 ◽  
Vol 50 (14) ◽  
pp. 1745-1747 ◽  
Author(s):  
Xiang Li ◽  
Fangzhi Peng ◽  
Mingtao Zhou ◽  
Mingjie Mo ◽  
Ruirui Zhao ◽  
...  
Keyword(s):  
Asymmetric Synthesis ◽  
Enantioselective Synthesis ◽  
Synthetic Methodology ◽  
Design And Synthesis ◽  
Catalytic Asymmetric Synthesis ◽  
Michael Acceptors ◽  
Catalytic Asymmetric

A catalytic enantioselective synthesis of 1,3-enynes for the development of nitro dienynes as novel Michael acceptors has been developed.

Rhodium catalysed enantioselective synthesis of mono-(halo)-methyl-cyclopropanes

2019 ◽  
Vol 17 (3) ◽  
pp. 472-476 ◽  
Author(s):  
Claire Schlinquer ◽  
Wei-Sheng Huang ◽  
Ling Chen ◽  
Thomas Poisson ◽  
Xavier Pannecoucke ◽  
...  
Keyword(s):  
Asymmetric Synthesis ◽  
Enantioselective Synthesis ◽  
Catalytic Asymmetric Synthesis ◽  
Catalytic Asymmetric

The catalytic asymmetric synthesis of mono-fluoro-, -chloro- and -bromomethyl-1,2-diaryl ester cyclopropanes is described.

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