Rhodium catalysed enantioselective synthesis of mono-(halo)-methyl-cyclopropanes

2019 ◽  
Vol 17 (3) ◽  
pp. 472-476 ◽  
Author(s):  
Claire Schlinquer ◽  
Wei-Sheng Huang ◽  
Ling Chen ◽  
Thomas Poisson ◽  
Xavier Pannecoucke ◽  
...  

The catalytic asymmetric synthesis of mono-fluoro-, -chloro- and -bromomethyl-1,2-diaryl ester cyclopropanes is described.

2014 ◽  
Vol 50 (14) ◽  
pp. 1745-1747 ◽  
Author(s):  
Xiang Li ◽  
Fangzhi Peng ◽  
Mingtao Zhou ◽  
Mingjie Mo ◽  
Ruirui Zhao ◽  
...  

A catalytic enantioselective synthesis of 1,3-enynes for the development of nitro dienynes as novel Michael acceptors has been developed.


2014 ◽  
Vol 12 (29) ◽  
pp. 5324-5330 ◽  
Author(s):  
Lara Cala ◽  
Francisco J. Fañanás ◽  
Félix Rodríguez

This perspective article summarizes the few and recently reported methods on catalytic asymmetric synthesis of spiroacetal derivatives from achiral substrates.


2018 ◽  
Vol 5 (9) ◽  
pp. 1542-1559 ◽  
Author(s):  
Pei-Gang Ding ◽  
Xiao-Si Hu ◽  
Feng Zhou ◽  
Jian Zhou

The catalytic asymmetric synthesis of α-chiral azides is of current interest and three synthetic strategies have been developed. This review summarizes the recent progress in this research area, discusses the advantages and limitations of each strategy, and outlines synthetic opportunities for future research.


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