A pyrene thiazole conjugate as a ratiometric chemosensor with high selectivity and sensitivity for tin (Sn4+) and its application in imaging live cells

RSC Advances ◽  
2014 ◽  
Vol 4 (100) ◽  
pp. 56605-56614 ◽  
Author(s):  
Ajit Kumar Mahapatra ◽  
Sanchita Mondal ◽  
Kalipada Maiti ◽  
Saikat Kumar Manna ◽  
Rajkishor Maji ◽  
...  

A new pyrene thiazole-conjugate amine based fluoroionophore, PTC was developed for ratiometric detection of Sn4+ ion in organo-aqueous medium.

The Analyst ◽  
2018 ◽  
Vol 143 (1) ◽  
pp. 250-257 ◽  
Author(s):  
Soham Samanta ◽  
Senjuti Halder ◽  
Poulomi Dey ◽  
Utsab Manna ◽  
Aiyagari Ramesh ◽  
...  

A new water soluble and fluorogenic probe (L) that can demonstrate the specific ratiometric detection of a SO2derivative (SO32−) in 100% aqueous medium and live cells has been designed and synthesized.


2017 ◽  
Vol 41 (16) ◽  
pp. 8026-8030 ◽  
Author(s):  
Xiang-Zhu Chen ◽  
Xiao-Dong Ma ◽  
Hong-Mei Wang ◽  
Mian Wang ◽  
Yuan-Yuan Zhang ◽  
...  

The new sensor containing oxime-ether can detect Pd2+with high sensitivity and high selectivity in aqueous medium.


2021 ◽  
Author(s):  
Shilpi Jaiswal ◽  
Subhankar Kundu ◽  
Sujoy Bandyopadhyay ◽  
Abhijit Patra

An organic–inorganic hybrid upconversion nanoprobe was developed for the real-time detection of aliphatic biogenic amines in an aqueous medium, adulterated milk, and rotten fish.


Author(s):  
Divya Singhal ◽  
Neha Gupta ◽  
Ashok Kumar Singh

4-(thiazol-2-yldiazenyl)phenol (L1) and 2-((4-hydroxyphenyl) diazenyl)-5-nitrophenol (L2) based on azo phenol were synthesised and used as selective colorimetric sensor for CN- and AcO− ion in DMSO/H2O-HEPES (v/v; 1:1, pH–7.3 ± 0.2) and showed good sensitivity with large red shifts and nanomolar detection limit for CN- and AcO- ion. The stoichiometry of L1 with CN−/AcO− ion was found to be 1:1 and L2 with CN−/AcO− ion was found to be 1:2. Binding constant for L1+ CN−, L1 + AcO−, L2 + CN− and L2 + AcO− were calculated by B-H plot as 1.6 × 103, 8.0 × 102, 8.4 × 103 and 1.7 × 102 respectively. L2 showed high selectivity towards CN− ion with low detection limit of 81 nM and large binding constant. In addition, 1H NMR titration and DFT studies also supported the deprotonation mechanism of receptors in the presence of selective anions.


2019 ◽  
Vol 11 (2) ◽  
pp. 232-235 ◽  
Author(s):  
Na Jiang ◽  
Bin Wang ◽  
Tao Liu ◽  
Qingyu Liu ◽  
Qin Wei ◽  
...  

A hemicyanine-based fluorescent dye, Mito-BT, was developed to ratiometrically detect H2S. This dye was of high selectivity, photostability and sensitivity with a rapid response time of 10 seconds. In addition, Mito-BT was localized in mitochondria, making it a promising probe for detecting H2S in cells.


2018 ◽  
Vol 42 (22) ◽  
pp. 18143-18151 ◽  
Author(s):  
Kwan Ho Jung ◽  
Semin Oh ◽  
Joohee Park ◽  
Yu Jin Park ◽  
See-Hyoung Park ◽  
...  

A fluorescent peptidyl probe based on a Cd(ii)-triggered self-assembling process was proposed for ratiometric detection for Cd(ii) in urine and live cells.


2021 ◽  
Vol 5 (1) ◽  
pp. 238-248
Author(s):  
S. Saravanan ◽  
Rafiq Ahmad ◽  
S. Kasthuri ◽  
Kunal Pal ◽  
S. Raviteja ◽  
...  

Pyrazoloanthrone functionalized copolymer exhibit high selectivity and sensitivity towards TNP in aqueous medium in presence of other competitive explosive analytes.


2017 ◽  
Vol 72 (1) ◽  
pp. 35-41 ◽  
Author(s):  
Yuling Xu ◽  
Stephen Opeyemi Aderinto ◽  
Huilu Wu ◽  
Hongping Peng ◽  
Han Zhang ◽  
...  

AbstractA new Schiff base, 4-allylamine-N-(N-5-methylsalicylidene)-1,8-naphthalimide (1), has been designed and synthesized by combining a 1,8-naphthalimide moiety as a fluorophore and a Schiff base as a recognition group. Its photophysical properties were investigated by absorption and fluorescence spectroscopy, and this sensor exhibits a high fluorescence quantum yield of 0.75–0.91 inorganic solvents of different polarity. It also shows high selectivity for Cu2+ over other ions with fluorescence quenching in aqueous medium (pH=7.2). The reason for this phenomenon (fluorescence quenching) is attributed to the formation of a 1:1 complex between 1 and Cu2+ according to the Job plot and fluorescence titration. The sensor can be applied to the quantification of Cu2+ in a linear fashion from 0.5 to 5 μM with a detection limit of 0.23 μM. Additionally, the association constant (Ka) between Cu2+ and 1 is 1.328×106 M−1 in aqueous media.


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