Divalent metal ions modulated strong frustrated M(ii)–Fe(iii)3O (M = Fe, Mn, Mg) chains with metamagnetism only in a mixed valence iron complex

2015 ◽  
Vol 51 (83) ◽  
pp. 15336-15339 ◽  
Author(s):  
Qi-Long Wu ◽  
Song-De Han ◽  
Qing-Lun Wang ◽  
Jiong-Peng Zhao ◽  
Feng Ma ◽  
...  

Using divalent ions to link the frustrated Fe(iii)3O units two isostructural chains were generated with distinct magnetic behaviour: frustrations and metamagnetism in mixed valence complex, but magnetic frustrations in heterometallic complexes.


1957 ◽  
Vol 3 (3) ◽  
pp. 411-417 ◽  
Author(s):  
I. J. McDonald

Growth of caseinate utilizing lactic streptococci in media with sodium caseinate as the nitrogen source was retarded by sodium acetate (40 mg./ml.) and by sodium citrate (10 mg./ml.). The inhibition caused by citrate was relieved by calcium or magnesium while that caused by acetate was relieved by calcium. In media with acid hydrolyzed casein as the nitrogen source, growth was inhibited in the presence of sodium citrate (10 mg./ml.) or disodium ethylene diamine tetraacetate (0.004 mg./ml.) but this inhibition was overcome by the addition of either calcium or magnesium. It appears, therefore, that these divalent ions were not required merely for activation of proteases produced by the organisms.



2017 ◽  
Vol 19 (40) ◽  
pp. 27611-27622 ◽  
Author(s):  
Biswajit Sadhu ◽  
Mahesh Sundararajan ◽  
Tusar Bandyopadhyay

The interplay between the hydration energy barrier and optimum site-selectivity controls the permeation and blocking features of divalent metal ions.



1980 ◽  
Vol 75 (5) ◽  
pp. 493-510 ◽  
Author(s):  
D J Adams ◽  
T M Dwyer ◽  
B Hille

The relative permeability of endplate channels to monovalent and divalent metal ions was determined from reversal potentials. Thallium is the most permeant ion with a permeability ratio relative to Na+ of 2.5. The selectivity among alkali metals is weak with a sequence, Cs+ greater than Rb+ greater than K+ greater than Na+ greater than Li+, and permeability ratios of 1.4, 1.3, 1.1, 1.0, and 0.9. The selectivity among divalent ions is also weak, with a sequence for alkaline earths of Mg++ greater than Ca++ greater than Ba++ greater than Sr++. The transition metal ions Mn++, Co++, Ni++, Zn++, and Cd++ are also permeant. Permeability ratios for divalent ions decreased as the concentration of divalent ion was increased in a manner consistent with the negative surface potential theory of Lewis (1979 J. Physiol. (Lond.). 286: 417--445). With 20 mM XCl2 and 85.5 mM glucosamine.HCl in the external solution, the apparent permeability ratios for the alkaline earth cations (X++) are in the range 0.18--0.25. Alkali metal ions see the endplate channel as a water-filled, neutral pore without high-field-strength sites inside. Their permeability sequence is the same as their aqueous mobility sequence. Divalent ions, however, have a permeability sequence almost opposite from their mobility sequence and must experience some interaction with groups in the channel. In addition, the concentrations of monovalent and divalent ions are increased near the channel mouth by a weak negative surface potential.



1991 ◽  
Vol 81 (4) ◽  
pp. 462-466 ◽  
Author(s):  
Maria Fabiana Drincovich ◽  
Alberto A. Iglesias ◽  
Carlos S. Andreo






RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12815-12825
Author(s):  
Yajie Wang ◽  
Feihong Meng ◽  
Tong Lu ◽  
Chunyun Wang ◽  
Fei Li

Their is a counteraction between a decrease in the disruptive ability of metal-associated oligomer species and an increase in the quantity of oligomers promoted by the metal binding in the activity of hIAPP induced membrane damage.



1981 ◽  
Vol 256 (16) ◽  
pp. 8582-8587
Author(s):  
M.J. Kronman ◽  
S.K. Sinha ◽  
K. Brew


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