Half-sandwich Ru(η6-C6H6) complexes with chiral aroylthioureas for enhanced asymmetric transfer hydrogenation of ketones – experimental and theoretical studies

2015 ◽  
Vol 5 (10) ◽  
pp. 4790-4799 ◽  
Author(s):  
Mani Mary Sheeba ◽  
Sankaranarayanan Preethi ◽  
A. Nijamudheen ◽  
Manoharan Muthu Tamizh ◽  
Ayan Datta ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Theoretical Studies ◽  
Asymmetric Transfer Hydrogenation ◽  
Experimental And Theoretical Studies ◽  
Half Sandwich

The efficiency of Ru–benzene complexes towards ATH of ketones was studied.

N,O- vs N,C-Chelation in Half-Sandwich Iridium Complexes: A Dramatic Effect on Enantioselectivity in Asymmetric Transfer Hydrogenation of Ketones

ACS Catalysis ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 8020-8026 ◽  
Author(s):  
Gang Zhou ◽  
Ahmed H. Aboo ◽  
Craig M. Robertson ◽  
Ruixia Liu ◽  
Zhenhua Li ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Iridium Complexes ◽  
Asymmetric Transfer Hydrogenation ◽  
Dramatic Effect ◽  
Half Sandwich

Half-Sandwich Complexes of Osmium(II) withl-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity

2012 ◽  
Vol 31 (8) ◽  
pp. 3333-3345 ◽  
Author(s):  
Daniel Carmona ◽  
Fernando J. Lahoz ◽  
Pilar García-Orduña ◽  
Luis A. Oro ◽  
M. Pilar Lamata ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Carboxylate Ligands ◽  
Hydrogenation Catalysts ◽  
Half Sandwich

Role of the sulfonamide moiety of Ru(II) half-sandwich complexes in the asymmetric transfer hydrogenation of 3,4-dihydroisoquinolines

2016 ◽  
Vol 118 (1) ◽  
pp. 215-222 ◽  
Author(s):  
Ondřej Matuška ◽  
Jakub Zápal ◽  
Radka Hrdličková ◽  
Miloš Mikoška ◽  
Jan Pecháček ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Sandwich Complexes ◽  
Half Sandwich
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