Is bond stretch isomerism in mononuclear transition metal complexes a real issue? The misleading case of the MoCl5/tetrahydropyran reaction system

2015 ◽  
Vol 44 (28) ◽  
pp. 12653-12659 ◽  
Author(s):  
Francesco Paolo Di Nicola ◽  
Massimiliano Lanzi ◽  
Fabio Marchetti ◽  
Guido Pampaloni ◽  
Stefano Zacchini
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Reaction System ◽  
Real Issue ◽  
System P ◽  
Bond Stretch

The MoCl5/tetrahydropyran reaction system provides an opportunity for discussing the possible generation of bond stretch isomers.

ChemInform Abstract: Bond-Stretch Isomerism in Transition-Metal Complexes.

ChemInform ◽  
1988 ◽  
Vol 19 (45) ◽  
Author(s):  
Y. JEAN ◽  
A. LLEDOS ◽  
J. K. BURDETT ◽  
R. HOFFMANN
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Bond Stretch

Bond-stretch isomerism in transition-metal complexes

1988 ◽  
Vol 110 (14) ◽  
pp. 4506-4516 ◽  
Author(s):  
Yves. Jean ◽  
Agusti. Lledos ◽  
Jeremy K. Burdett ◽  
Roald. Hoffmann
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Bond Stretch

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

Density Functional Calculations of EPR Parameter g Tensors of Some Transition Metal Complexes

2011 ◽  
Vol 2 (2) ◽  
pp. 139-141
Author(s):  
Vinita Prajapati ◽  
◽  
P.L.Verma P.L.Verma ◽  
Dhirendra Prajapati ◽  
B.K.Gupta B.K.Gupta
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional Calculations ◽  
Density Functional
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