Novel Anderson-type [TeMo6O24]6−-based metal–organic complexes tuned by different species and their coordination modes: assembly, various architectures and properties

2016 ◽  
Vol 45 (6) ◽  
pp. 2709-2719 ◽  
Author(s):  
Xiuli Wang ◽  
Junjun Sun ◽  
Hongyan Lin ◽  
Zhihan Chang ◽  
Aixiang Tian ◽  
...  
Keyword(s):  
Photocatalytic Properties ◽  
Coordination Modes ◽  
Organic Complexes ◽  
Metal Organic

Four novel Anderson-type polyoxometalate [TeMo6O24]6−-based metal–organic complexes were hydrothermally synthesized and characterized, which show fluorescence, electrochemical and photocatalytic properties.

Assembly and Properties of Four New Metal–Organic Complexes Based on 1,4-Naphthalenedicarboxylate: Effect of Four Bis-pyridyl-bis-amide Ligands with Diverse Spacers in the Structures

2015 ◽  
Vol 68 (10) ◽  
pp. 1550 ◽  
Author(s):  
Hong-Yan Lin ◽  
Xun-Zhang Zhao ◽  
Ling Zeng ◽  
Qing-Lin Wang ◽  
Xiu-Li Wang ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Photocatalytic Properties ◽  
Coordination Modes ◽  
Coordination Network ◽  
Amide Ligands ◽  
Hydrogen Bonding Interactions ◽  
Organic Complexes ◽  
3D Architecture ◽  
Metal Organic ◽  
Supramolecular Networks

Four new complexes based on 1,4-naphthalenedicarboxylic acid (1,4-H2NDC) and four bis-pyridyl-bis-amide ligands with various spacers (3-bpye = N,N′-bis(3-pyridinecarboxamide)-1,2-ethane; 3-bpfp = bis(3-pyridylformyl)piperazine; 3-bpcd = N,N′-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide; and 3-bpcb = N,N′-bis(3-pyridinecarboxamide)-1,4-benzene), namely [Cu2(1,4-NDC)2(3-bpye)(H2O)] (1), [Cu(1,4-NDC)(3-bpfp)0.5] (2), [Cu3(1,4-NDC)3(3-bpcd)3]·2H2O (3), and [Cu(1,4-NDC)(3-bpcb)] (4), have been hydrothermally synthesized. Complex 1 is a 3D coordination network and represents an 8-connected {420.68} topology. Complex 2 shows a 2-fold interpenetrating 3D architecture with a 6-connected {412.63} topology. Complexes 3 and 4 possess similar 2D sql layers with the {44.62} topology, but the coordination modes of 1,4-NDC ligands and the conformations of the two bis-pyridyl-bis-amide ligands are different. The adjacent layers for 3 and 4 are further linked by hydrogen bonding interactions to form 3D supramolecular networks. The successful assemblies of complexes 1–4 imply that by using the different bis-pyridyl-bis-amide ligands with diverse spacers can produce diverse metal–organic networks. Furthermore, the fluorescence and photocatalytic properties of complexes 1–4 have been investigated.

Two [TeMo6O24]6−-based metal-organic complexes derived by different N-site ligands: Architectures, electrochemical and photocatalytic properties

2020 ◽  
Vol 112 ◽  
pp. 107751
Author(s):  
Jiahui Li ◽  
Xue Bai ◽  
Hongyan Lin ◽  
Guocheng Liu ◽  
Xiang Wang ◽  
...  
Keyword(s):  
Photocatalytic Properties ◽  
Organic Complexes ◽  
Metal Organic

Effect of polyoxoanions and amide group coordination modes on the assembly of polyoxometalate-based metal–organic complexes constructed from a semi-rigid bis-pyridyl-bis-amide ligand

CrystEngComm ◽  
2015 ◽  
Vol 17 (4) ◽  
pp. 895-903 ◽  
Author(s):  
Xiuli Wang ◽  
Zhihan Chang ◽  
Hongyan Lin ◽  
Aixiang Tian ◽  
Guocheng Liu ◽  
...  
Keyword(s):  
Amide Group ◽  
Coordination Modes ◽  
Group Coordination ◽  
Organic Complexes ◽  
Metal Organic

Various amide-derived ligands induced five octamolybdate-based metal–organic complexes: synthesis, structure, electrochemical sensing and photocatalytic properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Xiuli Wang ◽  
Lei Li ◽  
Xiang Wang ◽  
Yuqing Zhang
Keyword(s):  
Electrochemical Sensors ◽  
Organic Ligands ◽  
Electrochemical Sensing ◽  
Photocatalytic Properties ◽  
Organic Complexes ◽  
Metal Organic

Five octamolybdate-based complexes with diverse architectures employing three new amide-derived organic ligands can be used as promising electrochemical sensors and photocatalysts.

Cooperative effects of metal cations and coordination modes on luminescent s-block metal–organic complexes constructed from V-shaped 4,4′-sulfonyldiphenol

CrystEngComm ◽  
2018 ◽  
Vol 20 (46) ◽  
pp. 7513-7525 ◽  
Author(s):  
Cheng Li ◽  
Zhao-Peng Deng ◽  
Li-Hua Huo ◽  
Shan Gao
Keyword(s):  
Solid State ◽  
Room Temperature ◽  
Metal Cations ◽  
Blue Luminescence ◽  
Coordination Modes ◽  
Cooperative Effects ◽  
Organic Complexes ◽  
Metal Organic ◽  
Supramolecular Networks

Thirteen s-block metal–organic complexes with different supramolecular networks arising from the coordination modes of the ligands and properties of the metal cations have been synthesized and exhibit violet and blue luminescence in the solid state at room temperature.

Interplay of coordinative and supramolecular interactions in formation of a series of metal–organic complexes bearing diverse dimensionalities

2009 ◽  
pp. 5365 ◽  
Author(s):  
Jian-Qiang Liu ◽  
Ya-Nan Zhang ◽  
Yao-Yu Wang ◽  
Jun-Cheng Jin ◽  
Elmira Kh. Lermontova ◽  
...  
Keyword(s):  
Supramolecular Interactions ◽  
Organic Complexes ◽  
Metal Organic

Syntheses, Crystal Structures, and Properties of Four Metal–Organic Complexes Based on 1,4,5,6,7,7-Hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic Acid

2015 ◽  
Vol 15 (9) ◽  
pp. 4198-4205 ◽  
Author(s):  
Jie Yang ◽  
Xiaobin Liu ◽  
Xiaoqing Wang ◽  
Fangna Dai ◽  
Yan Zhou ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Crystal Structures ◽  
Organic Complexes ◽  
Structures And Properties ◽  
Metal Organic
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