Composition-driven phase boundary and electrical properties in (Ba0.94Ca0.06)(Ti1–xMx)O3 (M = Sn, Hf, Zr) lead-free ceramics

2016 ◽  
Vol 45 (15) ◽  
pp. 6466-6480 ◽  
Author(s):  
Chunlin Zhao ◽  
Hui Wang ◽  
Jie Xiong ◽  
Jiagang Wu

In this study, we systematically investigated the composition dependence of the phase structure, microstructure, and electrical properties of (Ba0.94Ca0.06)(Ti1−xMx)O3 (M = Sn, Hf, Zr) ceramics synthesised by the conventional solid-state reaction method.

RSC Advances ◽  
2018 ◽  
Vol 8 (28) ◽  
pp. 15613-15620 ◽  
Author(s):  
Xiaochun He ◽  
Ruiqing Chu ◽  
Zhijun Xu ◽  
Zhongran Yao ◽  
Jigong Hao

Lead-free ceramics, SrBi2Nb2O9–xBi2O3 (SBN–xBi), with different Bi contents of which the molar ratio, n(Sr) : n(Bi) : n(Nb), is 1 : 2(1 + x/2) : 2 (x = −0.05, 0.0, 0.05, 0.10), were prepared by conventional solid-state reaction method.


RSC Advances ◽  
2015 ◽  
Vol 5 (25) ◽  
pp. 19647-19651 ◽  
Author(s):  
Yang Zhang ◽  
Lingyu Li ◽  
Wangfeng Bai ◽  
Bo Shen ◽  
Jiwei Zhai ◽  
...  

(1 − x)[0.93(K0.5Na0.5)NbO3–0.07LiNbO3]–xCaZrO3 (KNN–LN–xCZ) lead-free piezoelectric ceramics have been prepared by the conventional solid state reaction method and investigated to differentiate the effects of polymorphic phase transition.


RSC Advances ◽  
2016 ◽  
Vol 6 (40) ◽  
pp. 33387-33392 ◽  
Author(s):  
Zhongran Yao ◽  
Ruiqing Chu ◽  
Zhijun Xu ◽  
Jigong Hao ◽  
Guorong Li

Lead-free piezoelectric ceramics with the formula of Sr1−x(Li,Ce)x/2(Na0.5Bi0.5)Bi4Ti5O18 (LCSNBT-x, x = 0.0, 0.1, 0.2, 0.3, 0.4), were prepared by a conventional solid-state reaction method.


RSC Advances ◽  
2016 ◽  
Vol 6 (17) ◽  
pp. 13803-13808 ◽  
Author(s):  
Zhongran Yao ◽  
Ruiqing Chu ◽  
Zhijun Xu ◽  
Jigong Hao ◽  
Juan Du ◽  
...  

Bismuth layer-structured ferroelectrics with a formula of Sr1−x(K,Ce)x/2(Na0.5Bi0.5)Bi4Ti5O18, were prepared by a conventional solid-state reaction method.


2018 ◽  
Vol 6 (41) ◽  
pp. 19967-19973 ◽  
Author(s):  
Zhenyong Cen ◽  
Yu Huan ◽  
Wei Feng ◽  
Yan Yu ◽  
Peiyao Zhao ◽  
...  

Lead-free (1 − x)(0.96K0.46Na0.54Nb0.98Ta0.02O3–0.04Bi0.5(Na0.82K0.18)0.5ZrO3)–xCaZrO3 ((1 − x)(0.96KNNT–0.04BNKZ)–xCZ) piezoelectric ceramics were prepared by the conventional solid-state reaction method.


RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14504-14512
Author(s):  
H. Slimi ◽  
A. Oueslati ◽  
A. Aydi

(Ba0.95Ca0.05)1−x(Ti0.8Sn0.2)1−xNaxNbxO3 (BCNTSNO3) lead-free ceramics with compositions (x = 0.75, 0.8 and 0.85) were synthesized through the traditional solid-state reaction method.


2015 ◽  
Vol 44 (17) ◽  
pp. 7797-7802 ◽  
Author(s):  
Yang Zhang ◽  
Lingyu Li ◽  
Bo Shen ◽  
Jiwei Zhai

Lead free piezoelectric ceramics have been prepared by the conventional solid state reaction method and the effects of SrZrO3 content on polymorphic phase transition are investigated.


2016 ◽  
Vol 45 (20) ◽  
pp. 8573-8586 ◽  
Author(s):  
Wangfeng Bai ◽  
Daqin Chen ◽  
Peng Zheng ◽  
Bo Shen ◽  
Jiwei Zhai ◽  
...  

In this study, a lead-free ceramic system comprising (0.94 − x)Bi0.5Na0.5TiO3–0.06BaTiO3–xBi(Zn0.5Ti0.5)O3 (BNT–BT–BZT) was designed and prepared by a conventional solid-state reaction method.


RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2616-2623
Author(s):  
Weijie Zheng ◽  
Jiaqi Lin ◽  
Xinmei Liu ◽  
Wenlong Yang ◽  
Yuanshuo Li

(Ba0.85Ca0.15)(Zr0.1Ti0.9−xCex)O3+ySb ceramics prepared by the conventional solid-state reaction.


2018 ◽  
Vol 70 (3) ◽  
pp. 560-567 ◽  
Author(s):  
Jian Feng Li ◽  
Qin Shi ◽  
HeJun Zhu ◽  
ChenYu Huang ◽  
Shuai Zhang ◽  
...  

Purpose This paper aims to clarify the size and morphology of transition metal dichalcogenides has an impact on lubrication performance of Cu-based composites. This study is intended to show that Cu-based electrical contact materials containing Nb0.91Ti0.09Se2 have better electrical and tribological properties than those containing NbSe2. The tribological properties of Cu-based with different Ti-dopped NbSe2 content were also discussed. Design/methodology/approach The NbSe2 and Nb0.91Ti0.09Se2 particles were fabricated by thermal solid state reaction method. The powder metallurgy technique was used to fabricate composites with varying Nb0.91Ti0.09Se2 mass fraction. The phase composition of Cu-based composites was identified by X-ray diffraction, and the morphology of NbSe2/Nb0.91Ti0.09Se2 and the worn surface of composites were characterized by scanning electron microscopy and transmission electron microscopy. In addition, the tribological properties of composites were appraised using a ball-on-disk multi-functional tribometer. The data of friction coefficient and resistivity were analyzed and the corresponding conclusion was drawn. Findings In comparison with the pure copper, Cu-based composites containing Nb0.91Ti0.09Se2/NbSe2 had a lower friction coefficient, illustrating the Nb0.91Ti0.09Se2 with nano-size particles prepared in this work is a perfect choice for the fabrication of excellent electrical contact composites. Compared to composites with NbSe2, composites containing Nb0.91Ti0.09Se2 have better tribological and electrical properties. Research limitations/implications Because of the use of thermal solid state reaction method, the size of NbSe2 and Nb0.91Ti0.09Se2 is relatively large. Therefore, the fabrication of finer particles of Nb0.91Ti0.09Se2 is encouraged. Originality/value In this paper, the authors discuss the tribological and electrical properties of Cu-based composites, and the value of optimum obtained as Nb0.91Ti0.09Se2 content is 15 Wt.%.


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