Microwave-assisted fast conversion of lignin model compounds and organosolv lignin over methyltrioxorhenium in ionic liquids

RSC Advances ◽  
2015 ◽  
Vol 5 (103) ◽  
pp. 84967-84973 ◽  
Author(s):  
Bo Zhang ◽  
Changzhi Li ◽  
Tao Dai ◽  
George W. Huber ◽  
Aiqin Wang ◽  
...  

Fast depolymerization of β-O-4 model compounds and organosolv lignin to aromatic chemicals over methyltrioxorhenium in ionic liquids without oxidant/reducing agent under microwave irradiation is developed.

2014 ◽  
Vol 28 (2) ◽  
pp. 1380-1386 ◽  
Author(s):  
Jingying Pan ◽  
Jie Fu ◽  
Shuguang Deng ◽  
Xiuyang Lu

2020 ◽  
Vol 16 ◽  
Author(s):  
Mahdieh Sharifi ◽  
Ramyakrishna Pothu ◽  
Rajender Boddula ◽  
Inamuddin

Background: There is a developing demand for innovation in petroleum systems replacements. Towards this aim, lignocellulosic biomass suggested as a possible sustainable source for the manufacturing of fuels and produced chemicals. The aims of this paper are to investigate different kinds of β-O-4 lignin model compounds for the production of value-added chemicals in presence of ionic liquids. Especially, a cheap β-O-4 lignin model Guaiacol glycerol ether (GGE) (Guaifenesin) is introduced to produce valuable chemicals and novel products. Methods: Research related to chemical depolymerization of lignocellulosic biomass activity is reviewed, the notes from different methods such as thermal and microwave collected during at least 10 years. So, this collection provides a good source for academic research and it gives an efficient strategy for the manufacturing of novel value-added chemicals at an industrial scale. Results: This research presented that ionic liquid microwave-assisted is a power saving, cost efficient, fast reaction, and clean way with high selectively and purity for production of high value chemicals rather that conversional heating. Guaiacol and catechol are some of these valuable chemicals that is produced from β-O-4 lignin model compounds with high word demands that are capable to produce in industry scale. Conclusion: The β-O-4 lignin model compounds such as Guaiacol glycerol ether (GGE) (Guaifenesin) are good platform for developing food materials, perfumery, biorefinery, and pharmaceutical industry by ionic liquids-assisted lignin depolymerization method.


2017 ◽  
Vol 19 (19) ◽  
pp. 4538-4543 ◽  
Author(s):  
Jia-wei Zhang ◽  
Guo-ping Lu ◽  
Chun Cai

A MIL-100(Fe) supported Pd–Ni BMNP catalyst has been fabricated, and the catalyst exhibits superior catalytic performance toward intramolecular transfer hydrogenolysis of lignin model compounds and organosolv lignin.


2017 ◽  
Vol 46 (35) ◽  
pp. 11884-11889 ◽  
Author(s):  
Kang-kang Sun ◽  
Guo-ping Lu ◽  
Jia-wei Zhang ◽  
Chun Cai

β-O-4 and α-O-4 linkages can be selectively cleaved by Pd–Ni bimetallic nanoparticles in ionic liquids using hydrogen gas as the hydrogen donor under ambient pressure and neutral conditions.


2017 ◽  
Vol 53 (63) ◽  
pp. 8850-8853 ◽  
Author(s):  
Yingying Yang ◽  
Honglei Fan ◽  
Qinglei Meng ◽  
Zhaofu Zhang ◽  
Guanying Yang ◽  
...  

Ionic liquids can effectively induce the transformation of lignin model compounds into aromatic compounds by aerobic oxidation under metal-free conditions.


2015 ◽  
Vol 51 (19) ◽  
pp. 4028-4031 ◽  
Author(s):  
Yingying Yang ◽  
Honglei Fan ◽  
Jinliang Song ◽  
Qinglei Meng ◽  
Huacong Zhou ◽  
...  

Ionic liquid can efficiently promote the transformation of lignin model compounds and organosolv lignin.


2016 ◽  
Vol 18 (8) ◽  
pp. 2341-2352 ◽  
Author(s):  
Lu Chen ◽  
Jiayu Xin ◽  
Lingli Ni ◽  
Huixian Dong ◽  
Dongxia Yan ◽  
...  

A novel pseudo-homogeneous catalyst system consisting of noble metal nanoparticles and ionic liquids is developed for the selective reductive cleavage of C–O and hydrodeoxygenation under mild conditions.


2017 ◽  
Vol 121 (3) ◽  
pp. 1537-1545 ◽  
Author(s):  
Guodian Zhu ◽  
Meilu Lin ◽  
Di Fan ◽  
Wenshan Ning ◽  
Xinping Ouyang ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document