Multiferroic properties of Bi0.5K0.5TiO3–BiFe1−xCoxO3 (0 ≤ x ≤ 0.2) solid solution

RSC Advances ◽  
2015 ◽  
Vol 5 (126) ◽  
pp. 104210-104215 ◽  
Author(s):  
X. Z. Zuo ◽  
J. Yang ◽  
B. Yuan ◽  
X. C. Kan ◽  
Lin Zu ◽  
...  
Keyword(s):  
Solid Solution ◽  
Pechini Method ◽  
Ferroelectric Properties ◽  
Lead Free ◽  
Multiferroic Properties ◽  
Modified Pechini Method

We have successfully prepared a binary lead-free solid-solution of Bi0.5K0.5TiO3–BiFe1−xCoxO3 using a modified Pechini method and investigated the magnetic and ferroelectric properties of Bi0.5K0.5TiO3–BiFe1−xCoxO3 (0 ≤ x ≤ 0.2).

Crystal Growth and Electrical Properties of Na0.5Bi0.5TiO3-BaTiO3 Lead-Free Ferroelectric Piezocrystals

2009 ◽  
Vol 421-422 ◽  
pp. 17-20
Author(s):  
Chao Chen ◽  
Xiang Yong Zhao ◽  
Hong Liu ◽  
Wen Wei Ge ◽  
Hao Su Luo ◽  
...  
Keyword(s):  
Solid Solution ◽  
Crystal Growth ◽  
Electrical Properties ◽  
Crystal Orientation ◽  
Ferroelectric Properties ◽  
Lead Free ◽  
Depolarization Temperature ◽  
Dielectric Maximum ◽  
Top Seeded Solution Growth ◽  
Piezoelectric Performance

(1-x)(Na0.5Bi0.5)TiO3-xBaTiO3 (abbreviated as NBBT100(1-x)/100x or NBBT100x) solid solution single crystals with x=0, 0.06, 0.08, 0.10, 0.20, 1.0 were grown using top-seeded solution growth (TSSG) method. Dielectric, piezoelectric and ferroelectric properties of NBBT crystals were investigated as a function of temperature, frequency, composition and crystal orientation. The temperature (Tm) corresponding to dielectric maximum and the depolarization temperature (Td) decrease with increasing x. The <001> oriented NBBT90/10 single crystal shows excellent piezoelectric performance with piezoelectric constant (d33) value about 275pC/N and exhibits relatively smaller coercive field (Ec) of 2.49 kV/mm and dielectric loss tanδ of 2.9 %, indicating a more adaptive engineered domain structure.

Structure and Multiferroic Properties of Bi0.9Y0.1FeO3-PbTiO3 Ceramics

2010 ◽  
Vol 105-106 ◽  
pp. 263-265
Author(s):  
Bao Lin Feng ◽  
Chong Hai Wang ◽  
Chang Ling Zhou ◽  
Cheng Gong Sun ◽  
Zhao Xian Xiong ◽  
...  
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Bismuth Ferrite ◽  
Ferroelectric Properties ◽  
Dielectric Constants ◽  
Conventional Solid State Reaction ◽  
Multiferroic Properties ◽  
Ionic Substitution ◽  
Antiferromagnetic Ordering ◽  
Ceramic Samples

Bismuth ferrite, BiFeO3, was an important multiferroic material, which simultaneously exhibited ferroelectric ordering and antiferromagnetic ordering in the bulk form. The solid solutions of Bi0.9Y0.1FeO3 with PbTiO3 were prepared by the conventional solid state reaction. It was clear that in Bi0.9Y0.1FeO3-PbTiO3 solid solution, the structure remined rhobohedral for 85 mole% of Bi0.9Y0.1FeO3, from 80 to 70mole% it were rhobohedral and tetragonal, and below 65 mole%, the structure transformed to tetragonal. The dielectric and ferroelectric properties of the ceramics had been significantly improved by means of ionic substitution of Ti4+ for Fe3+, which reduced the electric conductivity. The dielectric constants of the ceramic samples were enhanced from 84 to 241 and the remnant polarizations were improved from 0.494 to 2.17 μC/cm2.

Piezoelectric, Dielectric and Ferroelectric Properties of (1−x)(K0.48Na0.52)0.95Li0.05Nb0.95Sb0.05O3-xBa0.5(Bi0.5Na0.5)0.5ZrO3 Lead-Free Solid Solution

2018 ◽  
Vol 47 (10) ◽  
pp. 6053-6058 ◽  
Author(s):  
Brenda Carreño-Jiménez ◽  
Armando Reyes-Montero ◽  
M. E. Villafuerte-Castrejón ◽  
Rigoberto López-Juárez
Keyword(s):  
Solid Solution ◽  
Ferroelectric Properties ◽  
Lead Free

Crystal structure and multiferroic properties of BiFeO3–Na0.5K0.5NbO3 solid solution ceramics prepared by Pechini method

2012 ◽  
Vol 68 ◽  
pp. 8-10 ◽  
Author(s):  
S.X. Huo ◽  
S.L. Yuan ◽  
Y. Qiu ◽  
Z.Z. Ma ◽  
C.H. Wang
Keyword(s):  
Crystal Structure ◽  
Solid Solution ◽  
Pechini Method ◽  
Multiferroic Properties

Characterization of new solid solution phases in (Y,Ca)(Cr,Co)O3 system

1995 ◽  
Vol 10 (1) ◽  
pp. 40-43 ◽  
Author(s):  
Cem Basceri ◽  
A. Cuneyt Tas ◽  
Muharrem Timucin
Keyword(s):  
Solid Solution ◽  
Powder Diffraction ◽  
Pechini Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Modified Pechini Method ◽  
Diffraction Patterns

New solid solution phases in the (Y,Ca)(Cr,Co)O3 system have been synthesized and characterized by powder X-ray diffraction. The selected compositions in this system were prepared by the modified Pechini method. Powder-diffraction patterns were prepared.

Correlation between structure, dielectric and multiferroic properties of lead free Ni modified BaTiO3 solid solution

2020 ◽  
Vol 46 (17) ◽  
pp. 27336-27351 ◽  
Author(s):  
M. Arshad ◽  
Wasi Khan ◽  
M. Abushad ◽  
M. Nadeem ◽  
Shahid Husain ◽  
...  
Keyword(s):  
Solid Solution ◽  
Lead Free ◽  
Multiferroic Properties

Thermal Expansion and Electrical Characteristics of Ba(1−x)CaxTi0.92Zr0.08O3 Lead-Free Ceramics Prepared by a Modified Pechini Method

2018 ◽  
Vol 47 (11) ◽  
pp. 6655-6662 ◽  
Author(s):  
Yongshang Tian ◽  
Shuiyun Li ◽  
Shulin Sun ◽  
Yansheng Gong ◽  
Shujie Sun ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Pechini Method ◽  
Lead Free ◽  
Electrical Characteristics ◽  
Lead Free Ceramics ◽  
Modified Pechini Method

X-ray powder diffraction data of LaNi0.5Ti0.45Co0.05O3, LaNi0.45Co0.05Ti0.5O3, and LaNi0.5Ti0.5O3 perovskites

2021 ◽  
pp. 1-6
Author(s):  
Mariana M. V. M. Souza ◽  
Alex Maza ◽  
Pablo V. Tuza
Keyword(s):  
Crystal Structure ◽  
Rietveld Method ◽  
Pechini Method ◽  
Powder Diffraction Data ◽  
X Ray Diffraction ◽  
Unit Cell Parameters ◽  
X Ray ◽  
Cell Parameters ◽  
Modified Pechini Method ◽  
Scanning Electron

In the present work, LaNi0.5Ti0.45Co0.05O3, LaNi0.45Co0.05Ti0.5O3, and LaNi0.5Ti0.5O3 perovskites were synthesized by the modified Pechini method. These materials were characterized using X-ray fluorescence, scanning electron microscopy, and powder X-ray diffraction coupled to the Rietveld method. The crystal structure of these materials is orthorhombic, with space group Pbnm (No 62). The unit-cell parameters are a = 5.535(5) Å, b = 5.527(3) Å, c = 7.819(7) Å, V = 239.2(3) Å3, for the LaNi0.5Ti0.45Co0.05O3, a = 5.538(6) Å, b = 5.528(4) Å, c = 7.825(10) Å, V = 239.5(4) Å3, for the LaNi0.45Co0.05Ti0.5O3, and a = 5.540(2) Å, b = 5.5334(15) Å, c = 7.834(3) Å, V = 240.2(1) Å3, for the LaNi0.5Ti0.5O3.

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