An unusual 32-membered copper(ii) metallomacrocube based on a Cu4O3X cubic core: photocatalytic, electrocatalytic, and magnetic properties

2016 ◽  
Vol 52 (23) ◽  
pp. 4294-4297 ◽  
Author(s):  
Sisi Feng ◽  
Fei Jia ◽  
Liping Lu ◽  
Zhongping Li ◽  
Shuo Zhang
Keyword(s):  
Magnetic Properties ◽  
Rhodamine B ◽  
Electrocatalytic Activity ◽  
Organic Pollutant ◽  
Catalytic Performance ◽  
Nitrite Reduction ◽  
Good Electrocatalytic Activity ◽  
Excellent Catalytic Performance

The first Cu32 cluster featuring a multi-cubane (Cu4O3X) structure exhibited excellent catalytic performance in the degradation of organic pollutant rhodamine B, good electrocatalytic activity for nitrite reduction, and strong antiferromagnetic interactions.

scholarly journals Catalysis of Organic Pollutants Abatement Based on Pt-Decorated Ag@Cu2O Heterostructures

Molecules ◽  
2019 ◽  
Vol 24 (15) ◽  
pp. 2721
Author(s):  
Xiaolong Zhang ◽  
Bingbing Han ◽  
Yaxin Wang ◽  
Yang Liu ◽  
Lei Chen ◽  
...  
Keyword(s):  
Catalytic Reduction ◽  
Structural Characteristics ◽  
Organic Pollutant ◽  
Pt Nanoparticles ◽  
Catalytic Performance ◽  
Pt Nanoparticle ◽  
Local Surface ◽  
Local Surface Plasmon Resonance ◽  
Cu2o Nanoparticles ◽  
Excellent Catalytic Performance

Pt-decorated Ag@Cu2O heterostructures were successfully synthesized using a simple and convenient method. The Pt nanoparticle density on the Ag@Cu2O can be controlled by changing the concentration of the Pt precursor. The synthesized Ag@Cu2O–Pt nanoparticles exhibited excellent catalytic performance, which was greatly affected by changes in the Ag@Cu2O–Pt structure. To optimize the material’s properties, the synthesized Ag@Cu2O–Pt nanoparticles were used to catalyze toxic pollutants and methyl orange (MO), and nontoxic products were obtained by catalytic reduction. The Pt-decorated Ag@Cu2O nanoparticles showed excellent catalytic activity, which significantly decreased the pollutant concentration when the nanoparticles were used for catalytic reduction. The redistribution of charge transfer is the nanoparticles’ main contribution to the catalytic degradation of an organic pollutant. This Pt-decorated Ag@Cu2O material has unique optical and structural characteristics that make it suitable for photocatalysis, local surface plasmon resonance, and peroxide catalysis.

2D tetragonal transition-metal phosphides: an ideal platform to screen metal shrouded crystals for multifunctional applications

Nanoscale ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 6776-6784
Author(s):  
Qinxi Liu ◽  
Jianpei Xing ◽  
Zhou Jiang ◽  
Xue Jiang ◽  
Yi Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Transition Metal ◽  
High Stability ◽  
Catalytic Performance ◽  
Good Ductility ◽  
Metal Phosphides ◽  
Transition Metal Phosphides ◽  
Excellent Catalytic Performance

The unique bonding feature of TM2Ps contributes to their high stability, excellent catalytic performance, good ductility, and abundant magnetic properties.

Fabrication and Excellent Catalytic Performance of Three-dimensional Ordered Mesoporous Molybdenum Oxides

2014 ◽  
Vol 29 (2) ◽  
pp. 124-130 ◽  
Author(s):  
Yu-Cheng DU ◽  
Guang-Wei ZHENG ◽  
Qi MENG ◽  
Li-Ping WANG ◽  
Hai-Guang FAN ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Catalytic Performance ◽  
Molybdenum Oxides ◽  
Ordered Mesoporous ◽  
Excellent Catalytic Performance

Co a Sm b O x Catalyst with Excellent Catalytic Performance for NH 3 Decomposition

2021 ◽  
Author(s):  
Cui‐Ping Wu ◽  
Zhao Jin ◽  
Kai Xu ◽  
Wei‐Wei Wang ◽  
Chun‐Jiang Jia
Keyword(s):  
Catalytic Performance ◽  
Excellent Catalytic Performance

PtPd nanoframes derived from Pd@PdPt core–shell rhombic dodecahedrals with excellent catalytic performance toward methanol oxidation

2021 ◽  
Author(s):  
Yangyang Ren ◽  
Chuanliang Li ◽  
Baosong Li ◽  
Fan Gao ◽  
Xinghua Zhang ◽  
...  
Keyword(s):  
Methanol Oxidation ◽  
Catalytic Properties ◽  
Catalytic Performance ◽  
Core Shell ◽  
Acid Environment ◽  
Excellent Catalytic Performance

PtPd nanoframes with excellent catalytic properties were obtained by etching Pd@PdPt core–shell RDs with Fe3+ in an acid environment.

Rational construction of hierarchical SAPO-34 with enhanced MTO performance without an additional meso/macropore template

2021 ◽  
Author(s):  
Yafei Liang ◽  
Beibei Gao ◽  
Lipeng Zhou ◽  
Xiaomei Yang ◽  
Tianliang Lu ◽  
...  
Keyword(s):  
Catalytic Performance ◽  
Mto Reaction ◽  
Rational Construction ◽  
Excellent Catalytic Performance

A facile approach has been developed to fabricate hierarchical SAPO-34 with large intracrystalline meso/macropores and excellent catalytic performance in the MTO reaction.

scholarly journals Fe3 Cluster Anchored on the C2N Monolayer for Efficient Electrochemical Nitrogen Fixation

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 974
Author(s):  
Bing Han ◽  
Haihong Meng ◽  
Fengyu Li ◽  
Jingxiang Zhao
Keyword(s):  
Nitrogen Fixation ◽  
First Principles ◽  
Catalytic Performance ◽  
Reduction Reaction ◽  
First Principles Calculations ◽  
Ammonia Gas ◽  
Nitrogen Reduction ◽  
Single Cluster ◽  
Excellent Catalytic Performance ◽  
Production Of Ammonia

Under the current double challenge of energy and the environment, an effective nitrogen reduction reaction (NRR) has become a very urgent need. However, the largest production of ammonia gas today is carried out by the Haber–Bosch process, which has many disadvantages, among which energy consumption and air pollution are typical. As the best alternative procedure, electrochemistry has received extensive attention. In this paper, a catalyst loaded with Fe3 clusters on the two-dimensional material C2N (Fe3@C2N) is proposed to achieve effective electrochemical NRR, and our first-principles calculations reveal that the stable Fe3@C2N exhibits excellent catalytic performance for electrochemical nitrogen fixation with a limiting potential of 0.57 eV, while also suppressing the major competing hydrogen evolution reaction. Our findings will open a new door for the development of non-precious single-cluster catalysts for effective nitrogen reduction reactions.

Amino-functionalized Cu-MOF for efficient purification of methane from light hydrocarbons and excellent catalytic performance

2019 ◽  
Vol 6 (5) ◽  
pp. 1152-1157 ◽  
Author(s):  
Xia Wang ◽  
Xiurong Zhang ◽  
Kai Zhang ◽  
Xiaokang Wang ◽  
Yutong Wang ◽  
...  
Keyword(s):  
Catalytic Performance ◽  
Light Hydrocarbons ◽  
Excellent Catalytic Performance

Amino-functionalized Cu-MOF for the efficient purification of methane from light hydrocarbons and excellent catalytic performance.

A core–shell structured magnetic Ag/AgBr@Fe2O3 composite with enhanced photocatalytic activity for organic pollutant degradation and antibacterium

RSC Advances ◽  
2015 ◽  
Vol 5 (87) ◽  
pp. 71035-71045 ◽  
Author(s):  
Shuquan Huang ◽  
Yuanguo Xu ◽  
Zhigang Chen ◽  
Meng Xie ◽  
Hui Xu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Photocatalytic Activity ◽  
Organic Pollutant ◽  
Core Shell ◽  
Pollutant Degradation ◽  
Antibacterial Ability ◽  
Highly Efficient ◽  
Organic Pollutant Degradation

A core–shell structured Ag/AgBr@Fe2O3 composite was prepared successfully. It has magnetic properties, highly efficient photocatalytic activity and antibacterial ability.

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