A binary catalyst system of a cationic Ru–CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide
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Binary catalyst systems comprising a cationic Ru–CNC pincer complex and an alkali metal salt were developed for selective hydroboration of CO2 at r.t. and 1 atm CO2, with [Ru(CNCBn)(CO)2(H)][PF6] and KOCO2tBu producing formoxyborane in 76% yield.
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2018 ◽
Vol 6
(5)
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pp. 6675-6681
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1975 ◽
Vol 30
(3-4)
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pp. 219-225
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2014 ◽
Vol 4
(6)
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pp. 1638-1643
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