The influence of solvent on the pre-exponential factor and interfacial energy based on the metastable zone width data

CrystEngComm ◽  
2016 ◽  
Vol 18 (34) ◽  
pp. 6358-6364 ◽  
Author(s):  
Lie-Ding Shiau
Keyword(s):  
Interfacial Energy ◽  
Exponential Factor ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone ◽  
Influence Of Solvent

scholarly journals A Linear Regression Model for Determining the Pre-Exponential Factor and Interfacial Energy Based on the Metastable Zone Width Data

Crystals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 103
Author(s):  
Lie-Ding Shiau
Keyword(s):  
Linear Regression ◽  
Regression Model ◽  
Interfacial Energy ◽  
Linear Regression Model ◽  
Nucleation Theory ◽  
Theory Approach ◽  
Exponential Factor ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

A linear regression model is presented in this study to determine the pre-exponential factor and interfacial energy of the crystallized substance based on classical nucleation theory using the metastable zone width data. The nucleation event is assumed corresponding to a point at which the total number density of the nuclei has reached a fixed (but unknown) value. One equation is derived for any temperature-dependent functional form of the solubility. Another equation is derived for the van’t Hoff solubility expression. The pre-exponential factor and interfacial energy obtained from these two equations are found consistent for the studied systems, including glutamic acid, glycine, and 3-nito-1,2,4-triazol-5-one. The results obtained from these two equations are also compared with those obtained from the integral method and classical 3D nucleation theory approach.

A model for determination of the interfacial energy from the induction time or metastable zone width data based on turbidity measurements

CrystEngComm ◽  
2014 ◽  
Vol 16 (41) ◽  
pp. 9743-9752 ◽  
Author(s):  
Lie-Ding Shiau ◽  
Tsan-Sheng Lu
Keyword(s):  
Interfacial Energy ◽  
Induction Time ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

A model is developed to recover the interfacial energy from the induction time and the metastable zone width data.

scholarly journals Determination of Metastable Zone Width, Induction Period and Interfacial Energy of a Ferroelectric Crystal - Potassium Ferrocyanide Trihydrate (KFCT)

2010 ◽  
Vol 7 (1) ◽  
pp. 137-142 ◽  
Author(s):  
R. Kanagadurai ◽  
R. Durairajan ◽  
R. Sankar ◽  
G. Sivanesan ◽  
S. P. Elangovan ◽  
...  
Keyword(s):  
Induction Period ◽  
Interfacial Energy ◽  
Growth Parameters ◽  
Visible Region ◽  
Potassium Ferrocyanide ◽  
Lemon Yellow ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone ◽  
Potassium Ferrocyanide Trihydrate

An order-disorder type potassium ferrocyanide trihydrate (KFCT) is a coordination compound forming lemon- yellow monoclinic ferroelectric crystals with curie temperature 251 K. KFCT crystals have been grown by temperature lowering solution growth technique. Solubility of KFCT has been determined for various temperatures. Metastable zone width, induction period and interfacial energy were determined for the aqueous solution of KFCT. Bulk crystal of potassium ferrocyanide trihydrate was grown with the optimized growth parameters. The grown crystal possesses good optical transmission in the entire UV-Visible region

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