Metastable zone width, induction period and interfacial energy of bis thiourea zinc acetate (BTZA)

2005 ◽  
Vol 276 (1-2) ◽  
pp. 243-246 ◽  
Author(s):  
D. Jayalakshmi ◽  
R. Sankar ◽  
R. Jayavel ◽  
J. Kumar
Keyword(s):  
Induction Period ◽  
Interfacial Energy ◽  
Zinc Acetate ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

scholarly journals Determination of Metastable Zone Width, Induction Period and Interfacial Energy of a Ferroelectric Crystal - Potassium Ferrocyanide Trihydrate (KFCT)

2010 ◽  
Vol 7 (1) ◽  
pp. 137-142 ◽  
Author(s):  
R. Kanagadurai ◽  
R. Durairajan ◽  
R. Sankar ◽  
G. Sivanesan ◽  
S. P. Elangovan ◽  
...  
Keyword(s):  
Induction Period ◽  
Interfacial Energy ◽  
Growth Parameters ◽  
Visible Region ◽  
Potassium Ferrocyanide ◽  
Lemon Yellow ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone ◽  
Potassium Ferrocyanide Trihydrate

An order-disorder type potassium ferrocyanide trihydrate (KFCT) is a coordination compound forming lemon- yellow monoclinic ferroelectric crystals with curie temperature 251 K. KFCT crystals have been grown by temperature lowering solution growth technique. Solubility of KFCT has been determined for various temperatures. Metastable zone width, induction period and interfacial energy were determined for the aqueous solution of KFCT. Bulk crystal of potassium ferrocyanide trihydrate was grown with the optimized growth parameters. The grown crystal possesses good optical transmission in the entire UV-Visible region

A model for determination of the interfacial energy from the induction time or metastable zone width data based on turbidity measurements

CrystEngComm ◽  
2014 ◽  
Vol 16 (41) ◽  
pp. 9743-9752 ◽  
Author(s):  
Lie-Ding Shiau ◽  
Tsan-Sheng Lu
Keyword(s):  
Interfacial Energy ◽  
Induction Time ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

A model is developed to recover the interfacial energy from the induction time and the metastable zone width data.

SUPERSATURATION, INDUCTION PERIOD, AND METASTABLE ZONE WIDTH OF CaCl2—Na2C03—HCl SYSTEM

2001 ◽  
Vol 188 (1) ◽  
pp. 243-263 ◽  
Author(s):  
CLIFFORD Y. TAI ◽  
WEN-CHEN CHIEN ◽  
JYH-PING HSU ◽  
CHUANG-CHUNG LEE
Keyword(s):  
Induction Period ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

Determination of Metastable Zone Width, Induction, Period and Interfacial Energy of (R)-3-(methylamino)-1-Phenylpropanol Hydrochloride

2011 ◽  
Vol 396-398 ◽  
pp. 950-954
Author(s):  
Liang Zhu ◽  
Rong Rong Lei ◽  
Yan Fei Wang ◽  
Li Bin Yang ◽  
Zuo Liang Sha
Keyword(s):  
Free Energy ◽  
Interfacial Tension ◽  
Induction Period ◽  
Atmospheric Pressure ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Period Data ◽  
Metastable Zone ◽  
Critical Nuclei

Solubility, metastable zone width and induction period of (R)-3-(methylamino)-1-phenylpropanol hydrochloride (MPH) in ethanol were determined by synthetic method at atmospheric pressure. The measured induction period data are also used to estimate the interfacial tension values of the system. The determined interfacial tension values have been also used to evaluate the nucleation parameters, such as the radius of the critical nuclei, the free energy change per unit volume, the critical free energy barriers.

scholarly journals A Linear Regression Model for Determining the Pre-Exponential Factor and Interfacial Energy Based on the Metastable Zone Width Data

Crystals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 103
Author(s):  
Lie-Ding Shiau
Keyword(s):  
Linear Regression ◽  
Regression Model ◽  
Interfacial Energy ◽  
Linear Regression Model ◽  
Nucleation Theory ◽  
Theory Approach ◽  
Exponential Factor ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Metastable Zone

A linear regression model is presented in this study to determine the pre-exponential factor and interfacial energy of the crystallized substance based on classical nucleation theory using the metastable zone width data. The nucleation event is assumed corresponding to a point at which the total number density of the nuclei has reached a fixed (but unknown) value. One equation is derived for any temperature-dependent functional form of the solubility. Another equation is derived for the van’t Hoff solubility expression. The pre-exponential factor and interfacial energy obtained from these two equations are found consistent for the studied systems, including glutamic acid, glycine, and 3-nito-1,2,4-triazol-5-one. The results obtained from these two equations are also compared with those obtained from the integral method and classical 3D nucleation theory approach.

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