The role of solid-state nuclear magnetic resonance in crystal engineering

CrystEngComm ◽  
2016 ◽  
Vol 18 (28) ◽  
pp. 5236-5252 ◽  
Author(s):  
Yijue Xu ◽  
Scott A. Southern ◽  
Patrick M. J. Szell ◽  
David L. Bryce
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Crystal Engineering ◽  
Solid State Nmr ◽  
Solid State Nmr Spectroscopy ◽  
Nuclear Magnetic

This Highlight article discusses the role of solid-state NMR spectroscopy in crystal engineering with the aid of several examples from the literature.

scholarly journals Recent Advances in Solid-State Nuclear Magnetic Resonance Spectroscopy

2018 ◽  
Vol 11 (1) ◽  
pp. 485-508 ◽  
Author(s):  
Sharon E. Ashbrook ◽  
John M. Griffin ◽  
Karen E. Johnston
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Solid State Nmr ◽  
Spectral Lines ◽  
Atomic Scale ◽  
Resonance Spectroscopy ◽  
Diverse Range ◽  
Nuclear Magnetic

The sensitivity of nuclear magnetic resonance (NMR) spectroscopy to the local atomic-scale environment offers great potential for the characterization of a diverse range of solid materials. Despite offering more information than its solution-state counterpart, solid-state NMR has not yet achieved a similar level of recognition, owing to the anisotropic interactions that broaden the spectral lines and hinder the extraction of structural information. Here, we describe the methods available to improve the resolution of solid-state NMR spectra and the continuing research in this area. We also highlight areas of exciting new and future development, including recent interest in combining experiment with theoretical calculations, the rise of a range of polarization transfer techniques that provide significant sensitivity enhancements, and the progress of in situ measurements. We demonstrate the detailed information available when studying dynamic and disordered solids and discuss the future applications of solid-state NMR spectroscopy across the chemical sciences.

Investigation of vanadia-alumina catalysts with solid-state NMR spectroscopy and DFT

2021 ◽  
Author(s):  
Evgeniy Papulovskiy ◽  
Aleksandr A. Shubin ◽  
Olga B. Lapina
Keyword(s):  
Experimental Data ◽  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Vanadium Oxide ◽  
Solid State Nmr ◽  
Alumina Surface ◽  
Solid State Nmr Spectroscopy ◽  
Surface Sites

In this work, isolated surface sites of vanadium oxide on alumina surface were modeled and compared to experimental data obtained with ⁵¹V Solid-State Nuclear Magnetic Resonance (SSNMR) spectroscopy. The geometry...

scholarly journals Recent Advances in Probing Host-Guest Interactions with Solid State Nuclear Magnetic Resonance

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ashlea Hughes ◽  
Frédéric Blanc
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Supramolecular Chemistry ◽  
Recent Advances ◽  
Nuclear Magnetic

An overview of the recent role of solid-state Nuclear Magnetic Resonance (NMR) spectroscopy in the field of supramolecular chemistry to probe host-guest interactions is provided. Over the last few years,...

scholarly journals Solid-state nuclear magnetic resonance characterization of the second generation of the UEC family of molecular sieves

2019 ◽  
Author(s):  
Heitor Secco Seleghini ◽  
Heloise de Oliveira Pastore ◽  
Fábio Aurélio Bonk
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Magnetic Resonance ◽  
Molecular Sieves ◽  
Solid State Nmr ◽  
Second Generation ◽  
3D Structures ◽  
Nuclear Magnetic

This work reports the characterization using solid-state NMR of the second generation of the UEC family of molecular sieves, such generation is composed by two tridimensional silicoaluminophosphates synthesized from a layered aluminophosphate (AlPO-CJ70). The 3D structures are analogous to SAPO-5 (UEC-4) and SAPO-15 (UEC-5), both were characterized using multinuclear solid-state NMR, 27Al-MQ-MAS and 29Si{27Al} TRAPDOR.

Role of cationic head-group in cytotoxicity of ionic liquids: Probing changes in bilayer architecture using solid-state NMR spectroscopy

2021 ◽  
Vol 581 ◽  
pp. 954-963
Author(s):  
Navleen Kaur ◽  
Markus Fischer ◽  
Sandeep Kumar ◽  
Gagandeep Kaur Gahlay ◽  
Holger A. Scheidt ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Head Group ◽  
Solid State Nmr Spectroscopy

Structural Characterization of Ca2+-ATPase-Bound Phospholamban in Lipid Bilayers by Solid-State Nuclear Magnetic Resonance (NMR) Spectroscopy†,‡

Biochemistry ◽  
2008 ◽  
Vol 47 (15) ◽  
pp. 4369-4376 ◽  
Author(s):  
Karsten Seidel ◽  
Ovidiu C. Andronesi ◽  
Joachim Krebs ◽  
Christian Griesinger ◽  
Howard S. Young ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Lipid Bilayers ◽  
Structural Characterization ◽  
Nuclear Magnetic

Analysis of 3,4-Methylenedioxy-N-Methylamphetamine (MDMA) in “Ecstasy” Tablets by13C Solid State Nuclear Magnetic Resonance (NMR) Spectroscopy

1999 ◽  
Vol 44 (4) ◽  
pp. 14550J ◽  
Author(s):  
Garry S. H. Lee ◽  
Don C. Craig ◽  
G. S. Kamali Kannangara ◽  
Michael Dawson ◽  
Costa Conn ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Nuclear Magnetic

Probing the Role of the Ceramide Acyl Chain Length and Sphingosine Unsaturation in Model Skin Barrier Lipid Mixtures by 2H Solid-State NMR Spectroscopy

Langmuir ◽  
2015 ◽  
Vol 31 (17) ◽  
pp. 4906-4915 ◽  
Author(s):  
Sören Stahlberg ◽  
Barbora Školová ◽  
Perunthiruthy K. Madhu ◽  
Alexander Vogel ◽  
Kateřina Vávrová ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Chain Length ◽  
Solid State Nmr ◽  
Acyl Chain ◽  
Skin Barrier ◽  
Solid State Nmr Spectroscopy ◽  
Acyl Chain Length ◽  
Lipid Mixtures

scholarly journals Surface enhanced dynamic nuclear polarization solid-state NMR spectroscopy sheds light on Brønsted–Lewis acid synergy during the zeolite catalyzed methanol-to-hydrocarbon process

2019 ◽  
Vol 10 (39) ◽  
pp. 8946-8954 ◽  
Author(s):  
Abhishek Dutta Chowdhury ◽  
Irina Yarulina ◽  
Edy Abou-Hamad ◽  
Andrei Gurinov ◽  
Jorge Gascon
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Lewis Acid ◽  
Dynamic Nuclear Polarization ◽  
Solid State Nmr ◽  
Nuclear Polarization ◽  
Solid State Nmr Spectroscopy ◽  
Surface Enhanced ◽  
Methanol To Hydrocarbon

Surface-enhanced dynamic nuclear polarization solid-state NMR spectroscopy has been applied to identify the role of surface-carbene species and elucidating Brønsted–Lewis acid synergy during the zeolite-catalyzed methanol-to-hydrocarbon process.

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