scholarly journals Tuning the photochemical properties of the fulvalene-tetracarbonyl-diruthenium system

2016 ◽  
Vol 45 (21) ◽  
pp. 8740-8744 ◽  
Author(s):  
Anders Lennartson ◽  
Angelica Lundin ◽  
Karl Börjesson ◽  
Victor Gray ◽  
Kasper Moth-Poulsen

In a Molecular Solar–Thermal Energy Storage (MOST) system, solar energy is converted to chemical energy using a compound that undergoes reversible endothermic photoisomerization.

2022 ◽  
Author(s):  
Maria Quant ◽  
Andreas Erbs Hillers-Bendtsen ◽  
Shima Ghasemi ◽  
Mate Erdelyi ◽  
Zhihang Wang ◽  
...  

Molecular solar-thermal energy storage (MOST) systems are based on photoswitches that reversibly convert solar energy into chemical energy. In this context, bicyclooctadienes (BOD) undergo a photoinduced transformation to the corresponding...


2019 ◽  
Vol 7 (25) ◽  
pp. 15042-15047 ◽  
Author(s):  
Zhihang Wang ◽  
Raul Losantos ◽  
Diego Sampedro ◽  
Masa-aki Morikawa ◽  
Karl Börjesson ◽  
...  

Molecules capable of reversible storage of solar energy have recently attracted increasing interest. Here, a liquid azobenzene molecule has been studied for solar thermal energy storage applications and integrated into flow-chemistry devices.


2019 ◽  
Author(s):  
Karolina Matuszek ◽  
R. Vijayaraghavan ◽  
Craig Forsyth ◽  
Surianarayanan Mahadevan ◽  
Mega Kar ◽  
...  

Renewable energy has the ultimate capacity to resolve the environmental and scarcity challenges of the world’s energy supplies. However, both the utility of these sources and the economics of their implementation are strongly limited by their intermittent nature; inexpensive means of energy storage therefore needs to be part of the design. Distributed thermal energy storage is surprisingly underdeveloped in this context, in part due to the lack of advanced storage materials. Here, we describe a novel family of thermal energy storage materials based on pyrazolium cation, that operate in the 100-220°C temperature range, offering safe, inexpensive capacity, opening new pathways for high efficiency collection and storage of both solar-thermal energy, as well as excess wind power. We probe the molecular origins of the high thermal energy storage capacity of these ionic materials and demonstrate extended cycling that provides a basis for further scale up and development.


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