scholarly journals Metal–ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand

2016 ◽  
Vol 45 (40) ◽  
pp. 16033-16039 ◽  
Author(s):  
Linda E. Eijsink ◽  
Sébastien C. P. Perdriau ◽  
Johannes G. de Vries ◽  
Edwin Otten
Keyword(s):  
Ruthenium Complex ◽  
Pincer Ligand ◽  
Pincer Complex ◽  
Cooperative Activation ◽  
Metal Ligand

Metal–ligand cooperative activation of nitriles by a de-aromatized Ru pincer complex leads to equilibrium mixtures (tautomers) as a result of ligand deprotonation by the Brønsted basic Ru-ketimido moiety.

Rh(I) Complex with a Tridentate Pyridine–Amino–Olefin Actor Ligand–Metal–Ligand Cooperative Activation of CO2 and Phenylisocyanate under C–C and Rh–E (E = O, N) Bond Formation

2019 ◽  
Vol 38 (8) ◽  
pp. 1787-1799 ◽  
Author(s):  
Isabell Heuermann ◽  
Benjamin Heitmann ◽  
Rasmus Stichauer ◽  
Daniel Duvinage ◽  
Matthias Vogt
Keyword(s):  
Bond Formation ◽  
Cooperative Activation ◽  
Metal Ligand

scholarly journals Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation

2013 ◽  
Vol 32 (15) ◽  
pp. 4114-4121 ◽  
Author(s):  
Bernhard Bichler ◽  
Christian Holzhacker ◽  
Berthold Stöger ◽  
Michael Puchberger ◽  
Luis F. Veiros ◽  
...  
Keyword(s):  
Heterolytic Cleavage ◽  
Pincer Complex ◽  
Metal Ligand

scholarly journals Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex

2016 ◽  
Vol 7 (4) ◽  
pp. 2579-2586 ◽  
Author(s):  
David Bézier ◽  
Changjian Guan ◽  
Karsten Krogh-Jespersen ◽  
Alan S. Goldman ◽  
Maurice Brookhart
Keyword(s):  
Computational Study ◽  
Rhodium Complex ◽  
Pincer Ligand ◽  
Alkane Dehydrogenation ◽  
Pincer Complex

A rhodium complex based on the bis-phosphine carbazolide pincer ligand was investigated in the context of alkane dehydrogenation and in comparison with its iridium analogue.

Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclic thione) (SCS-NHT) Pd pincer complex

2015 ◽  
Vol 44 (32) ◽  
pp. 14475-14482 ◽  
Author(s):  
Ginger E. Tyson ◽  
Kenan Tokmic ◽  
Casey S. Oian ◽  
Daniel Rabinovich ◽  
Henry U. Valle ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Photophysical Properties ◽  
Pincer Ligand ◽  
Pincer Complex

The first SCS-NHT pincer ligand and its Pd complex.

scholarly journals Front Cover: Metal‐ligand cooperative activation of HX (X=H, Br, OR) bond on Mn based pincer complexes (14/2021)

2021 ◽  
Vol 647 (14) ◽  
pp. 1397-1397
Author(s):  
Annika M. Krieger ◽  
Vivek Sinha ◽  
Adarsh V. Kalikadien ◽  
Evgeny A. Pidko
Keyword(s):  
Pincer Complexes ◽  
Front Cover ◽  
Cooperative Activation ◽  
Metal Ligand

Crystalline Cu(ii) metal–organic frameworks based on a carboxamide pincer ligand and an NCONCON–Pd(ii) pincer complex

CrystEngComm ◽  
2021 ◽  
Author(s):  
Siphelele S. P. Malaza ◽  
Gift Mehlana ◽  
Ocean Cheung ◽  
Roger Hunter ◽  
Banothile C. E. Makhubela
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Organometallic Complexes ◽  
Carbon Dioxide Conversion ◽  
Pincer Ligand ◽  
Pincer Complex ◽  
Metal Organic

Two copper MOFs based on carboxamide linkers are presented. This work shows how organometallic complexes with carboxylate functionalities can be repurposed to produce crystalline MOFs which can be used in carbon dioxide conversion.

Ruthenium complexes bearing an unsymmetrical pincer ligand with a 2-hydroxypyridylmethylene fragment: active catalysts for transfer hydrogenation of ketones

2016 ◽  
Vol 45 (11) ◽  
pp. 4828-4834 ◽  
Author(s):  
Jing Shi ◽  
Bowen Hu ◽  
Dawei Gong ◽  
Shu Shang ◽  
Guangfeng Hou ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Pincer Ligand ◽  
Hydrogenation Activity ◽  
Catalytic Transfer ◽  
Metal Ligand

The synthesis, reactivity and catalytic transfer hydrogenation activity of three metal–ligand cooperative ruthenium(ii) complexes (3–5) with a 2-hydroxypyridylmethylene fragment are reported.

Improved synthesis of pincer ligand precursor, and synthesis and structural characterization of terphenyl scaffolded S–C–S palladium pincer complex

2009 ◽  
Vol 12 (12) ◽  
pp. 1171-1174 ◽  
Author(s):  
Paul M. Schroder ◽  
Thomas F. Spilker ◽  
Wilson Luu ◽  
James B. Updegraff ◽  
Man Lung Kwan ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Pincer Ligand ◽  
Pincer Complex
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