scholarly journals Design of bifunctional quaternary phosphonium salt catalysts for CO2 fixation reaction with epoxides under mild conditions

2016 ◽  
Vol 18 (17) ◽  
pp. 4611-4615 ◽  
Author(s):  
Shiyao Liu ◽  
Naoki Suematsu ◽  
Keiji Maruoka ◽  
Seiji Shirakawa
Keyword(s):  
Co2 Fixation ◽  
Phosphonium Salt ◽  
Cyclic Carbonates ◽  
Efficient Synthesis ◽  
Reaction Conditions ◽  
Mild Conditions ◽  
Phosphonium Iodide ◽  
Fixation Reaction ◽  
Quaternary Phosphonium Salt

An efficient synthesis of cyclic carbonates from epoxides and CO2 under mild reaction conditions was achieved via the use of a designed bifunctional quaternary phosphonium iodide catalyst.

An efficient CO2 fixation reaction with epoxides catalysed by in situ formed blue vanadium catalyst from dioxovanadium(+5) complex: moisture enhanced and atmospheric oxygen retarded catalytic activity

2020 ◽  
Vol 44 (6) ◽  
pp. 2547-2554 ◽  
Author(s):  
Rakhimoni Borah ◽  
Naranarayan Deori ◽  
Sanfaori Brahma
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Co2 Fixation ◽  
Atmospheric Oxygen ◽  
Carbon Dioxide Fixation ◽  
Vanadium Catalyst ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Fixation Reaction

In situ formed vanadium(+4) species catalyzed carbon dioxide fixation reaction, leading to 99% conversion of epoxides to cyclic carbonates under mild conditions is reported here, along with the study on the in situ formed catalyst to some extent.

A new 2D lanthanum based microporous MOF for efficient synthesis of cyclic carbonates through CO2 fixation

2021 ◽  
Author(s):  
Sabuj Kanti Das ◽  
Anirban Ghosh ◽  
Sudip Bhattacharjee ◽  
Avik Chowdhury ◽  
Partha Mitra ◽  
...  
Keyword(s):  
Rare Earth ◽  
Co2 Fixation ◽  
High Efficiency ◽  
Rare Earth Metals ◽  
Metal Organic Frameworks ◽  
Cyclic Carbonates ◽  
Efficient Synthesis ◽  
Metal Organic ◽  
Fixation Reaction ◽  
Positively Charged

Metal-organic frameworks (MOFs) containing multiple carboxylate and sulfonate linkers together with positively charged rare earth metals can offer new opportunities in heterogeneous catalysis. High efficiency of CO2 fixation reaction at...

Macroporous polystyrene degraded and functionalized chromium MPS-Cr(iii)-alen complex as a sustainable porous catalyst for CO2 fixation under atmospheric pressure and selective oxidation of aromatic alkenes

2020 ◽  
Vol 44 (32) ◽  
pp. 13852-13862
Author(s):  
Priyanka Paul ◽  
Noor Salam ◽  
Aslam Khan ◽  
Debasis Das ◽  
Seikh Mafiz Alam ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Atmospheric Pressure ◽  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Porous Catalyst ◽  
Mild Conditions ◽  
Benign Synthesis

The benign synthesis of porous polystyrene supported chromium(iii) catalyst has been carried out for the production of cyclic carbonates via CO2 fixation under atm. pressure and for the selective oxidation of aromatic alkenes under mild conditions.

Binary metal-organic frameworks: Catalysts for the efficient solvent-free CO2 fixation reaction via cyclic carbonates synthesis

2019 ◽  
Vol 571 ◽  
pp. 1-11 ◽  
Author(s):  
Jintu Francis Kurisingal ◽  
Yadagiri Rachuri ◽  
Yunjang Gu ◽  
Ga-Hyeong Kim ◽  
Dae-Won Park
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Cyclic Carbonates ◽  
Binary Metal ◽  
Metal Organic ◽  
Fixation Reaction

CO2 fixation at atmospheric pressure: porous ZnSnO3 nanocrystals as a highly efficient catalyst for the synthesis of cyclic carbonates

RSC Advances ◽  
2016 ◽  
Vol 6 (37) ◽  
pp. 31153-31160 ◽  
Author(s):  
Susmita Roy ◽  
Biplab Banerjee ◽  
Asim Bhaumik ◽  
Sk. Manirul Islam
Keyword(s):  
Atmospheric Pressure ◽  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Reaction Conditions ◽  
Efficient Catalyst ◽  
Zinc Stannate ◽  
Highly Efficient ◽  
Self Assembled

Self-assembled, ultra small, porous zinc stannate nanocrystals have been synthesized, which catalyzes the formation of cyclic carbonates from various epoxide and CO2 under very mild reaction conditions.

Silanol-Enriched Viologen-Based Ionic Porous Hybrid Polymers for Efficient Catalytic CO2 Fixation into Cyclic Carbonates under Mild Conditions

2019 ◽  
Vol 7 (19) ◽  
pp. 16907-16916 ◽  
Author(s):  
Yadong Zhang ◽  
Ke Liu ◽  
Lei Wu ◽  
Hu Zhong ◽  
Niu Luo ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Hybrid Polymers ◽  
Mild Conditions

Poly(ionic liquid)s with high density of nucleophile /electrophile for CO2 fixation to cyclic carbonates at mild conditions

2019 ◽  
Vol 32 ◽  
pp. 281-289 ◽  
Author(s):  
Yaqiang Xie ◽  
Jun Liang ◽  
Yawen Fu ◽  
Ju Lin ◽  
Hongtao Wang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Co2 Fixation ◽  
High Density ◽  
Cyclic Carbonates ◽  
Mild Conditions ◽  
Poly Ionic Liquid

An imidazolium-functionalized mesoporous cationic metal–organic framework for cooperative CO2 fixation into cyclic carbonate

2018 ◽  
Vol 54 (4) ◽  
pp. 342-345 ◽  
Author(s):  
Jun Liang ◽  
Ya-Qiang Xie ◽  
Xu-Sheng Wang ◽  
Qiang Wang ◽  
Tao-Tao Liu ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Cyclic Carbonate ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Co Catalyst ◽  
Mild Conditions ◽  
Catalyst Free ◽  
Metal Organic ◽  
Organic Framework

A mesoporous cationic Cr-based metal–organic framework (MOF), FJI-C10, has been obtained and exhibited excellent performances in chemical fixation of CO2 into cyclic carbonates under co-catalyst free and mild conditions.

Synthesis of α-alkylidene cyclic carbonates via CO2 fixation under ambient conditions promoted by an easily available silver carbamate

2021 ◽  
Vol 45 (9) ◽  
pp. 4340-4346 ◽  
Author(s):  
Giulio Bresciani ◽  
Marco Bortoluzzi ◽  
Claudia Ghelarducci ◽  
Fabio Marchetti ◽  
Guido Pampaloni
Keyword(s):  
Co2 Fixation ◽  
Cyclic Carbonates ◽  
Ambient Conditions ◽  
Mild Conditions ◽  
Silver Carbamate

A series of α-alkylidene cyclic carbonates has been synthesized under mild conditions using silver carbamate Ag(O2CNEt2) in combination with PPh3.

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