Synthesis of degradable poly(ε-caprolactone)-based graft copolymers via a “grafting-from” approach

2016 ◽  
Vol 7 (46) ◽  
pp. 7126-7134 ◽  
Author(s):  
Panagiotis Bexis ◽  
Anthony W. Thomas ◽  
Craig A. Bell ◽  
Andrew P. Dove
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Grafting From

The controlled ring-opening polymerisation (ROP) of α-bromo-ε-caprolactone (αBrCL), a derivative of ε-caprolactone (εCL), and its copolymerisation with εCL is reported.

Synthesis of novel types of graft copolymers by a “grafting-from” method using ring-opening polymerization of lactones and lactides

2003 ◽  
Vol 57 (2-3) ◽  
pp. 137-146 ◽  
Author(s):  
Miroslav Janata ◽  
Bohumil Masař ◽  
Luděk Toman ◽  
Petr Vlček ◽  
Petra Látalová ◽  
...  
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Ring Opening Polymerization ◽  
Grafting From

Block and graft copolymers based on cationic ring-opening polymerizations

1992 ◽  
Vol 64 (1) ◽  
pp. 113-120 ◽  
Author(s):  
Eric J. Goethals ◽  
Veska Toncheva ◽  
Fried'l Hosteaux ◽  
Saskia Walraedt ◽  
Ronny de Clercq
Keyword(s):  
Ring Opening ◽  
Graft Copolymers

Synthesis of biodegradable protein–poly(ε-caprolactone) conjugates via enzymatic ring opening polymerization

2020 ◽  
Vol 11 (3) ◽  
pp. 682-686 ◽  
Author(s):  
Chunyang Bao ◽  
Xiaoling Xu ◽  
Jing Chen ◽  
Qiang Zhang
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Ring Opening Polymerization ◽  
Amphiphilic Graft Copolymers

Lipase–poly(HEAA) conjugates act as initiators and catalysts simultaneously for the eROP of ε-CL, forming biodegradable conjugates with amphiphilic graft copolymers.

scholarly journals An ε-caprolactone-derived 2-oxazoline inimer for the synthesis of graft copolymers

2020 ◽  
Vol 11 (42) ◽  
pp. 6847-6852
Author(s):  
Jungyeon Kim ◽  
Christopher Waldron ◽  
Beatrice Cattoz ◽  
C. Remzi Becer
Keyword(s):  
Ring Opening ◽  
Graft Copolymers ◽  
Starting Material

An inimer-like structure that consists of a 2-oxazoline ring for cationic ring opening polymerisation and a typical alpha-bromo ester initiator for Cu-RDRP has been synthesised using ε-Caprolactone as the starting material.

Graft copolymers containing poly(3-hydroxyalkanoates) — A review on their synthesis, properties, and applications

2008 ◽  
Vol 86 (6) ◽  
pp. 570-578 ◽  
Author(s):  
Sophie Nguyen
Keyword(s):  
Graft Copolymer ◽  
Main Chain ◽  
Graft Copolymers ◽  
Preparation Methods ◽  
Synthesis Properties ◽  
Grafting Through ◽  
Grafting From ◽  
Grafting Onto

The use of the poly(3-hydroxyalkanoates) in copolymer synthesis has received much interest, as the microbial polyester segments can bring interesting properties, such as biodegradability and biocompatibility. The synthesis, properties, and applications of graft copolymers containing poly(3-hydroxyalkanoates) as main chain or branches are reviewed here, with emphasis on the different preparation methods, which fit into the three main synthesis strategies of graft copolymers: “grafting onto”, “grafting from”, and “grafting through” or macromonomer methods.Key words: poly(3-hydroxyalkanoates), graft copolymer, synthesis, properties, applications.

PHEA-g-PDMAEA well-defined graft copolymers: SET-LRP synthesis, self-catalyzed hydrolysis, and quaternization

2016 ◽  
Vol 7 (45) ◽  
pp. 6973-6979 ◽  
Author(s):  
Fangxu Sun ◽  
Chun Feng ◽  
Haoyu Liu ◽  
Xiaoyu Huang
Keyword(s):  
Raft Polymerization ◽  
Graft Copolymers ◽  
Side Chains ◽  
Grafting From

This article reports the synthesis of well-defined graft copolymers containing a PHEA backbone and degradable PDMAEA side chains, by the combination of RAFT polymerization, SET-LRP, and the grafting-from strategy.

Sign in / Sign up

Export Citation Format

Share Document