In ancient Greek times, philosophers recognized just four elements—earth, water, air, and fire—all of which survive in the astrological classification of the 12 signs of the zodiac. At least some of these philosophers believed that these different elements consisted of microscopic components with differing shapes and that this explained the various properties of the elements. These shapes or structures were believed to be in the form of Platonic solids (figure 1.1) made up entirely of the same two-dimensional shape. The Greeks believed that earth consisted of microscopic cubic particles, which explained why it was difficult to move earth. Meanwhile, the liquidity of water was explained by an appeal to the smoother shape possessed by the icosahedron, while fire was said to be painful to the touch because it consisted of the sharp particles in the form of tetrahedra. Air was thought to consist of octahedra since that was the only remaining Platonic solid. A little later, a fifth Platonic solid, the dodecahedron, was discovered, and this led to the proposal that there might be a fifth element or “quintessence,” which also became known as ether. Although the notion that elements are made up of Platonic solids is regarded as incorrect from a modern point of view, it is the origin of the very fruitful notion that macroscopic properties of substances are governed by the structures of the microscopic components of which they are comprised. These “elements” survived well into the Middle Ages and beyond, augmented with a few others discovered by the alchemists, the precursors of modern-day chemists. One of the many goals of the alchemists seems to have been the transmutation of elements. Not surprisingly, perhaps, the particular transmutation that most enticed them was the attempt to change the base metal lead into the noble metal gold, whose unusual color, rarity, and chemical inertness have made it one of the most treasured substances since the dawn of civilization.
One-Pot Synthesis of Dimethyl Carbonate over a Binary Catalyst of an Ionic Liquid and an Alkali Carbonate under Low Pressure
