Silica-aerogel-powders “jammed” polyimide aerogels with excellent hydrophobicity and conversion to ultra-light polyimide aerogel

RSC Advances ◽  
2016 ◽  
Vol 6 (63) ◽  
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Shuai Wu ◽  
Ai Du ◽  
Youlai Xiang ◽  
Mingfang Liu ◽  
Tiemin Li ◽  
...  

In this paper, SAp play a role as the shrinkage inhibiter to fabricate the SAp “jammed” polyimide gels.

2018 ◽  
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Young H. Kim ◽  
Je K. Lee ◽  
Hae-Jin Hwang

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Song He ◽  
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Zhi Li ◽  
Congcong Li ◽  
...  

2019 ◽  
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Jin Wang ◽  
Yu Du ◽  
Jianhe Liao ◽  
Xuetong Zhang

1995 ◽  
Vol 28 (3) ◽  
pp. 581-587 ◽  
Author(s):  
T Rettelbach ◽  
J Sauberlich ◽  
S Korder ◽  
J Fricke

1995 ◽  
Vol 186 ◽  
pp. 278-284 ◽  
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J. Säuberlich ◽  
S. Korder ◽  
J. Fricke

2020 ◽  
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Hong Chen ◽  
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Tuhua Zhong ◽  
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Xianxu Zhan ◽  
...  

AbstractThe aim of the study was to develop a simple and cost-effective method to improve thermal insulation and hydrophobicity of wood. Herein, we attempted to use commercially available silica aerogel powders suspended in ethanol to treat the wood by a simple vacuum impregnation process. The effects of particle size (20 µm and 40 nm) of silica aerogels and the number of impregnation cycles (1, 3, and 5 cycles) were examined on the thermal conductivity and the surface hydrophobicity. The results showed that the thermal conductivity of silica aerogel-impregnated wood decreased by approximately 38%. The water contact angle of the impregnated wood increased up to the maximum values 153° with a comparison with 80° of the untreated wood, indicating effective hydrophobization after silica aerogel impregnation. The tensile properties of the impregnated wood were found slightly improved. The results indicate that the impregnation of silica aerogel powders in wood can be a facile and efficient approach to prepare wood with thermal insulation and hydrophobicity, which may hold great promise to be employed in manufacturing wood-based materials used in interior decoration and buildings.


Author(s):  
Sudeep M. Rao ◽  
Joshua Samuel ◽  
Sai S. Prakash ◽  
C. Jeffrey Brinker

Ambient pressure silica aerogel thin films have recently been prepared by exploiting reversible drying shrinkage caused by derivatization of the internal gel surface. Aerogels have porosities of upto 99.9% and due to the small size of the pores (few nanometers), large capillary stresses are produced in gels that are partially saturated with a wetting liquid. As a result of these capillary stresses, the flexible silica network undergoes strain which has been observed using environmental microscopy. This technique allows variation of the equilibrium vapor pressure and temperature, and a simultaneous monitoring of the deformation of the unconstrained film thickness. We have observed >600% deformation during the pore-filling and pore-emptying cycles. In this presentation, we discuss the unique stress-strain behavior of these films.Ref.: Sai S. Prakash, C. Jeffrey Brinker, Alan J. Hurd & Sudeep M. Rao, "Silica aerogel films prepared at ambient pressure by using surface derivatization to induce reversible drying shrinkage", Nature. Vol. 374, 30 March, 1995, 439-443.


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