Effect of Stabilizer on Gold Leaching with Thiourea in Alkaline Solutions

The present work investigated the comparison of the effects of Na2SO3 and Na2SiO3 on thiourea stabilization, and a systematic study was undertaken to establish the effects of these stabilizers on the stability of alkaline thiourea, both qualitatively and quantitatively. The effects of these stabilizers on the activation energy of alkaline thiourea gold leaching was also studied. The results showed that sodium silicate was more suitable as a stabilizer in this system than sodium sulfite because the peak current of gold dissolution with sodium sulfite was higher than that with sodium silicate, but the inhibition of thiourea decomposition by the former was less obvious than that of sodium silicate in the cyclic voltammetry curve. The quartz crystal microbalance results showed that the quality decreased to about 100 ng cm2 in the presence of a stabilizer, while it increased to 300 ng cm2 in the absence of the stabilizer. It is inferred that gold can be dissolved by alkaline thiourea in the presence of a stabilizer, while it cannot without a stabilizer because of the decomposition of thiourea. This assumption was confirmed by atomic force microscopy measurements. The surface activation energy of Au dissolution decreased from 183.76 to 98.07 kJ/moL with the addition of sodium silicate, indicating that Au dissolution was promoted with the chemical.

Properties and Engineering Applications of a New Goaf Grouting Filling Material

In the treatment of goafs in traffic engineering, technical problems such as those related to large-volume grouting and the precise control of material properties are often encountered. To address these issues, we developed a new composite material comprising cement-fly ash-modified sodium silicate (C-FA-MS). The setting time, fluidity, unconfined compressive strength, and microstructure were varied for different proportions of cement-sodium silicate (C-S) slurry, cement-fly ash-sodium silicate (C-FA-S) slurry, and C-FA-MS slurry, and their performances were compared and analysed. The experimental results showed that the initial setting time of the slurry was the shortest when both the original sodium silicate volume ratio ( V S ) and modified sodium silicate volume ratio ( V MS ) were 0.2. The final setting time of the C-S and C-FA-S slurries tended to decrease but then increased with decrease in V S , while that of the C-FA-MS slurry increased with lower V MS . The fluidity of the C-FA-S and C-FA-MS slurries decreased with decrease in V S or V MS at different fly ash admixture ratios. The consolidation compressive strength of C-S increased with decreasing V S , while that of C-FA-S showed a considerable increase only when V S decreased from 0.4 to 0.2. Meanwhile, the compressive strength of the C-FA-MS concretions first increased and then decreased with decrease in V MS . Microstructural analysis revealed that there were more cracks in the C-S agglomerate, the fly ash in the C-FA-S agglomerate reduced the relative density of the skeletal structure, and the stronger cross-linking in the C-FA-MS agglomerate improved the strength of the agglomerate. Under the condition of unit grouting volume, the cost of the C-FA-MS slurry was approximately 44.7% and 31.3% lower than that of the C-S and C-FA-S slurries, respectively. The new C-FA-MS material was applied for the treatment of the goaf in the Wu Sizhuang coal mine. Core drilling detection and audiofrequency magnetotelluric survey revealed that the goaf was sufficiently filled.

Effect of sodium hydroxide concentration on the compressive strength of geopolymer mortar using fly ash PLTU Tanjungjati B Jepara

Geopolymer concrete is concrete that uses environmentally friendly materials, using fly ash from waste materials from the coal industry as a substitute for cement. To produce geopolymer concrete, an alkaline activator is required, with a mixture of Sodium Hydroxide and Sodium Silicate. This research is an experimental study to determine the effect of variations in the concentration of sodium hydroxide (NaOH) 8 Mol, 10 Mol, 12 Mol, and 14 Mol on the compressive strength of geopolymer concrete. Mortar Geopolymer uses a mixture of 1: 3 for the ratio of fly ash and sand, 2.5: 0.45 for the ratio of sodium silicate and sodium hydroxide as an alkaline solution. The specimens used a cube mold having dimension 5 cm x 5 cm x 5 cm, then tested at 7 days and 28 days. The test resulted that concentration of NaOH 12 Mol obtained the maximum compressive strength of geopolymer concrete, that is 38.54 MPa. At concentrations of 12 Mol NaOH and exceeding 12M, the compressive strength of geopolymer concrete decreased.