Core–shell Co@SiO2 nanosphere immobilized Ag nanoparticles for hydrogen evolution from ammonia borane

RSC Advances ◽  
2016 ◽  
Vol 6 (92) ◽  
pp. 89450-89456 ◽  
Author(s):  
Qilu Yao ◽  
Zhang-Hui Lu ◽  
Yujuan Hu ◽  
Xiangshu Chen

Silver nanoparticles anchored on core–shell Co@SiO2 nanospheres (Co@SiO2/Ag) have been facilely prepared by using an in situ generated approach, and exhibited higher catalytic activity than their monometallic counterparts for the hydrolysis of AB.

RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 28947-28955 ◽  
Author(s):  
Halil Durak ◽  
Mehmet Gulcan ◽  
Mehmet Zahmakiran ◽  
Saim Ozkar ◽  
Murat Kaya

Nanohydroxyapatite-supported ruthenium(0) nanoparticles formed in situ during the hydrolysis of AB have been found to be a highly active catalyst in the generation of hydrogen from aqueous AB solution.


2016 ◽  
Vol 852 ◽  
pp. 252-256
Author(s):  
Wei Dong Qi ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Yong Jin Zou ◽  
Hai Liang Chu

Ammonia borane received extensive attention due to its hydrogen content as high as 19.6%. In present article we prepared the Pt-Co/C catalyst via ultrasonic immersion method and in situ reduction method. The catalyst was characterized by measuring the specific area. The influence of the catalyst on the properties of the hydrolysis of ammonia borane was tested, and the catalytic activity of the catalyst in cycle use was verified. Results shows that the catalytic activity of Pt0.5Co0.5/C is the highest, and the maximum hydrogen generation rate is 7229.613 mL/ (g ·min). It was verified that it remained good catalytic activity after cycle use for more than 10 times.


2015 ◽  
Vol 3 (32) ◽  
pp. 16663-16669 ◽  
Author(s):  
Heng Shen ◽  
Chunting Duan ◽  
Jing Guo ◽  
Ning Zhao ◽  
Jian Xu

Ag nanoparticles are in situ decorated on a BNNS modified with a TA–Fe complex, and the nanohybrids show excellent catalytic activity.


2020 ◽  
Vol 8 (16) ◽  
pp. 7724-7732 ◽  
Author(s):  
Yao Chen ◽  
Dong Yang ◽  
Benbing Shi ◽  
Wei Dai ◽  
Hanjie Ren ◽  
...  

Octahedral MOF@COF core–shell hetero-framework photocatalysts were designed which achieved superior photocatalytic H2-evolution activity.


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