Enhanced hydrogen generation by reverse spillover effects over bicomponent catalysts

The contribution of the reverse spillover effect to hydrogen generation reactions is still controversial. Herein, the promotion functions for reverse spillover in the ammonia borane hydrolysis reaction are proven by constructing a spatially separated NiO/Al2O3/Pt bicomponent catalyst via atomic layer deposition and performing in situ quick X-ray absorption near-edge structure (XANES) characterization. For the NiO/Al2O3/Pt catalyst, NiO and Pt nanoparticles are attached to the outer and inner surfaces of Al2O3 nanotubes, respectively. In situ XANES results reveal that for ammonia borane hydrolysis, the H species generated at NiO sites spill across the support to the Pt sites reversely. The reverse spillover effects account for enhanced H2 generation rates for NiO/Al2O3/Pt. For the CoOx/Al2O3/Pt and NiO/TiO2/Pt catalysts, reverse spillover effects are also confirmed. We believe that an in-depth understanding of the reverse effects will be helpful to clarify the catalytic mechanisms and provide a guide for designing highly efficient catalysts for hydrogen generation reactions.

Defect-Rich Walnut-like Copper-Doped Ni(PO3)2 Catalyst towards Ammonia Borane Electrooxidation Reaction with High Performance

Ammonia borane (NH3BH3, AB), a carbon-free-energy material has attracted enormous attention not only as the hydrogen storage source but also as the anodic fuel for direct AB fuel cells (DABFCs)....

Catalytic and mechanistic studies of a highly active and E-selective Co(II) PNNH pincer catalyst system for transfer-semihydrogenation of internal alkynes

Herein we report the application of a Co(II) PNNH pincer catalyst system (PNNH = 2-(5-(t-butyl)-1H-pyrazol-3-yl)-6-(dialkylphosphinomethyl)pyridine) for the highly E-selective transfer semihydrogenation of internal diaryl alkynes using methanol and ammonia borane...