Heterogeneous Cu(ii)/l-His@Fe3O4 nanocatalyst: a novel, efficient and magnetically-recoverable catalyst for organic transformations in green solvents

RSC Advances ◽  
2016 ◽  
Vol 6 (95) ◽  
pp. 92387-92401 ◽  
Author(s):  
Masoomeh Norouzi ◽  
Arash Ghorbani-Choghamarani ◽  
Mohsen Nikoorazm

A novel, efficient and green Cu(ii)/l-His@Fe3O4 catalyst has been applied successfully in the synthesis of heterocyclic compounds.

2019 ◽  
Vol 16 (6) ◽  
pp. 447-453 ◽  
Author(s):  
Leticia Lafuente ◽  
María Florencia Rochetti ◽  
Rodolfo Bravo ◽  
Leandro Sasiambarrena ◽  
Cintia C. Santiago ◽  
...  

Cu-Fe spinels promoted the Ferrier rearrangement of 2-nitroglycals with several O-nucleophiles. 2,3-Unsaturated carbohydrate derivatives were prepared by the reaction of 3,4,6-tri-Oacetyl- 2-nitroglucal and alcohols in the presence of 5 % of CuFe2O4. After separation of the catalyst with an external magnet, the reaction products were obtained in good yields and high stereo and regioselectivity. Also, S- and heterocyclic C-3 substituted 2-nitro-endo-glycals could be prepared by this method.


2020 ◽  
Vol 43 (1) ◽  
pp. 184-199
Author(s):  
Mohammad Abdollahi-Alibeik ◽  
Najmeh Gharibpour ◽  
Zahra Ramazani

AbstractA palladium complex of a dendrimer type ligand of aminoethylacrylamide immobilized onto the mesoporous channels of MCM-41 with magnetic core was prepared and characterized using various techniques such as XRD, TEM, BET, FT-IR, TGA, and VSM. The prepared nanostructured material was found as a magnetically recoverable catalyst for Heck reaction of aryl halides and vinylic C–H. The catalyst is easily recoverable with an external magnet and is reusable with different leaching amounts depending to loading of Pd. A hot filtration test was also performed and gave evidence that Palladium in heterogeneous samples can dissolve and then redeposit on the surface of the support material.


2018 ◽  
Vol 10 (5) ◽  
pp. 1591-1606 ◽  
Author(s):  
Julia C. M. Willig ◽  
Alexandra A. Amaral ◽  
Jamal Rafique ◽  
Sumbal Saba ◽  
Stefany Valiati ◽  
...  

Nano Letters ◽  
2008 ◽  
Vol 8 (3) ◽  
pp. 931-934 ◽  
Author(s):  
Jianping Ge ◽  
Tuan Huynh ◽  
Yongxing Hu ◽  
Yadong Yin

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