Palladium(0) nanoparticles supported on polydopamine coated Fe3O4 as magnetically isolable, highly active and reusable catalysts for hydrolytic dehydrogenation of ammonia borane

RSC Advances ◽  
2016 ◽  
Vol 6 (104) ◽  
pp. 102035-102042 ◽  
Author(s):  
Joydev Manna ◽  
Serdar Akbayrak ◽  
Saim Özkar

Palladium(0) nanoparticles supported on polydopamine coated magnetic ferrite nanopowders are highly active and reusable catalyst in hydrogen generation from the hydrolysis of ammonia borane with a turnover frequency of 14.5 min−1 at 25.0 ± 0.1 °C.

2017 ◽  
Vol 41 (14) ◽  
pp. 6546-6552 ◽  
Author(s):  
Serdar Akbayrak ◽  
Oğuzcan Taneroğlu ◽  
Saim Özkar

Co0/CeO2 is a magnetically separable and highly reusable catalyst in the hydrolysis of ammonia borane.


2016 ◽  
Vol 45 (27) ◽  
pp. 10969-10978 ◽  
Author(s):  
Serdar Akbayrak ◽  
Yalçın Tonbul ◽  
Saim Özkar

Ruthenium(0) nanoparticles supported on ceria (Ru0/CeO2) were in situ generated from the reduction of ruthenium(iii) ions impregnated on ceria during the hydrolysis of ammonia borane.


RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 28947-28955 ◽  
Author(s):  
Halil Durak ◽  
Mehmet Gulcan ◽  
Mehmet Zahmakiran ◽  
Saim Ozkar ◽  
Murat Kaya

Nanohydroxyapatite-supported ruthenium(0) nanoparticles formed in situ during the hydrolysis of AB have been found to be a highly active catalyst in the generation of hydrogen from aqueous AB solution.


2009 ◽  
Vol 1217 ◽  
Author(s):  
Önder Metin ◽  
Saim Özkar

AbstractWater soluble poly(4-styrenesulfonic acid-co-maleic acid), PSSA-co-MA, stabilized nickel(0) and cobalt(0) nanoclusters were prepared for the first time from the reduction of nickel(II) chloride and cobalt(II) chloride by using minimum amount of sodium borohydride shortly before their usage as catalysts in the hydrolysis of ammonia-borane (AB) in the same medium at room temperature. PSSA-co-MA stabilized nickel(0) and cobalt(0) nanoclusters showed high catalytic activity in hydrogen generation from the hydrolysis of AB even at low temperature.


RSC Advances ◽  
2014 ◽  
Vol 4 (26) ◽  
pp. 13742-13748 ◽  
Author(s):  
Serdar Akbayrak ◽  
Serap Gençtürk ◽  
İzzet Morkan ◽  
Saim Özkar

Rhodium(0) nanoparticles supported on nanotitania as a highly active catalyst in hydrogen generation from the hydrolysis of ammonia borane.


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