High efficiency planar Sn–Pb binary perovskite solar cells: controlled growth of large grains via a one-step solution fabrication process

2017 ◽  
Vol 5 (9) ◽  
pp. 2360-2367 ◽  
Author(s):  
Lingang Li ◽  
Fan Zhang ◽  
Yuying Hao ◽  
Qinjun Sun ◽  
Zhanfeng Li ◽  
...  

A well-controlled one-step method, assisted by sec-butyl alcohol solvent engineering and N,N-dimethylformamide solvent annealing under an N2 atmosphere, is developed for the growth of a high quality CH3NH3Pb(1−x)SnxI3 perovskite film.

2020 ◽  
Vol 8 (36) ◽  
pp. 12560-12567
Author(s):  
Linlin Qiu ◽  
Lika Dong ◽  
Deqiang Mei ◽  
Wei-Hsiang Chen ◽  
Lixin Song ◽  
...  

Perovskite films can be prepared using sec-butyl alcohol (2-BA) by a one-step antisolvent assisted method.


2017 ◽  
Vol 54 (4) ◽  
pp. 58-68
Author(s):  
A. Ivanova ◽  
A. Tokmakov ◽  
K. Lebedeva ◽  
M. Roze ◽  
I. Kaulachs

Abstract Organometal halide perovskites are promising materials for lowcost, high-efficiency solar cells. The method of perovskite layer deposition and the interfacial layers play an important role in determining the efficiency of perovskite solar cells (PSCs). In the paper, we demonstrate inverted planar perovskite solar cells where perovskite layers are deposited by two-step modified interdiffusion and one-step methods. We also demonstrate how PSC parameters change by doping of charge transport layers (CTL). We used dimethylsupoxide (DMSO) as dopant for the hole transport layer (PEDOT:PSS) but for the electron transport layer [6,6]-phenyl C61 butyric acid methyl ester (PCBM)) we used N,N-dimethyl-N-octadecyl(3-aminopropyl)trimethoxysilyl chloride (DMOAP). The highest main PSC parameters (PCE, EQE, VOC) were obtained for cells prepared by the one-step method with fast crystallization and doped CTLs but higher fill factor (FF) and shunt resistance (Rsh) values were obtained for cells prepared by the two-step method with undoped CTLs.


2018 ◽  
Vol 6 (47) ◽  
pp. 24036-24044 ◽  
Author(s):  
Yan Guo ◽  
Xiong He ◽  
Xin Liu ◽  
Xin Li ◽  
Leilei Kang

One-step implementation of plasmon enhancement and solvent annealing effects via introducing a Au NR suspension leads to more efficient PSCs under ambient conditions.


2019 ◽  
Vol 7 (32) ◽  
pp. 19008-19016 ◽  
Author(s):  
Yuxiao Guo ◽  
Xingtian Yin ◽  
Jie Liu ◽  
Wenxiu Que

An efficient and facile one-step spin-coating method assisted by a preheating process was applied for the fabrication of high-quality CsPbIBr2 films.


Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1521
Author(s):  
Jiabin Hao ◽  
Zeming Wang ◽  
Huiying Hao ◽  
Guanlei Wang ◽  
Hongcheng Gao ◽  
...  

So far, it is still a great challenge to prepare high efficiency organic–inorganic perovskite solar cells in ambient air. Specifically, moisture is easily combined with the perovskite material during the spin-coating process, which result in porous perovskite films with poor surface morphology. In this study, we investigated crystalline Ag-doped perovskite films by a one-step spin-coating method in air with 30–40% relative humidity (RH), in which ethyl acetate (EA) was used as antisolvent can absorb moisture in air to reduced nucleation density. More significantly, EA is a feasible and environmentally friendly solvent to replace highly toxic solvent. Moreover, 1.0% Ag-doped device shows a highest power conversion efficiency (PCE) of 14.36%. The improved performance is not only ascribed to the superior CH3NH3PbI3 film with high crystallinity but to the versatile tunability of energy band structure.


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