Highly selective transfer hydrogenation of α,β-unsaturated carbonyl compounds using Cu-based nanocatalysts

2017 ◽  
Vol 7 (13) ◽  
pp. 2828-2837 ◽  
Author(s):  
Nazia Siddqui ◽  
Bipul Sarkar ◽  
Chandrashekar Pendem ◽  
Rubina khatun ◽  
L. N. Sivakumar Konthala ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Selective Transfer ◽  
Unsaturated Alcohols

Simultaneous dehydrogenation of cyclohexanol to cyclohexanone and hydrogenation of α,β-unsaturated carbonyl compounds to corresponding α,β-unsaturated alcohols was carried out in a single pot reaction without addition of any external hydrogen donor.

Magnesium Aluminate Supported Cu Catalyst for Selective Transfer Hydrogenation of Biomass Derived Furfural to Furfuryl Alcohol with Formic Acid as Hydrogen Donor

2019 ◽  
Vol 4 (1) ◽  
pp. 145-151 ◽  
Author(s):  
Peddinti Nagaiah ◽  
Paleti Gidyonu ◽  
Muppala Ashokraju ◽  
Madduluri Venkata Rao ◽  
Prathap Challa ◽  
...  
Keyword(s):  
Formic Acid ◽  
Furfuryl Alcohol ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Magnesium Aluminate ◽  
Selective Transfer ◽  
Cu Catalyst

scholarly journals Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor

2019 ◽  
Vol 21 (15) ◽  
pp. 5867-5872 ◽  
Author(s):  
Deliang Zhang ◽  
Tomohiro Iwai ◽  
Masaya Sawamura
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Selective Transfer

Highly Selective Transfer Hydrogenation of Carbonyl Compounds Using La2O3

2018 ◽  
Vol 91 (11) ◽  
pp. 1561-1569 ◽  
Author(s):  
Taufik Abdillah Natsir ◽  
Takayoshi Hara ◽  
Nobuyuki Ichikuni ◽  
Shogo Shimazu
Keyword(s):  
Carbonyl Compounds ◽  
Transfer Hydrogenation ◽  
Selective Transfer

Selective Transfer Hydrogenation of Carbonyl Compounds by Ruthenium Nanoclusters Supported on Alkali-Exchanged Zeolite β.

ChemInform ◽  
2007 ◽  
Vol 38 (5) ◽  
Author(s):  
M. Lakshmi Kantam ◽  
B. Purna Chandra Rao ◽  
B. M. Choudary ◽  
B. Sreedhar
Keyword(s):  
Carbonyl Compounds ◽  
Transfer Hydrogenation ◽  
Selective Transfer ◽  
Zeolite Β

scholarly journals Iridium-Catalyzed Transfer Hydrogenation of Ketones and Aldehydes Using Glucose as a Sustainable Hydrogen Donor

Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 503 ◽  
Author(s):  
Masato Yoshida ◽  
Ryota Hirahata ◽  
Takayoshi Inoue ◽  
Takuya Shimbayashi ◽  
Ken-ichi Fujita
Keyword(s):  
Catalytic System ◽  
Carbonyl Compounds ◽  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Environmentally Benign ◽  
Iridium Catalyst ◽  
Hydrogenation Reactions

A new catalytic system for transfer hydrogenation of carbonyl compounds using glucose as a hydrogen donor was developed. Various ketones and aldehydes were efficiently converted to corresponding alcohols with two equivalents of glucose in the presence of a small amount (0.1 to 1.0 mol%) of iridium catalyst that had a functional ligand. In this catalytic system, transfer hydrogenation reactions proceeded based on the cooperativity of iridium and a functional ligand. It should be noted that environmentally benign water could have been used as a solvent in the present catalytic system for the reduction of various carbonyl substrates. Furthermore, the reaction scope could be extended by using N,N-dimethylacetamide as a reaction solvent.

Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

2020 ◽  
Vol 22 (11) ◽  
pp. 3323-3357 ◽  
Author(s):  
Ronald A. Farrar-Tobar ◽  
Andrea Dell'Acqua ◽  
Sergey Tin ◽  
Johannes G. de Vries
Keyword(s):  
Carbonyl Compounds ◽  
State Of The Art ◽  
The State ◽  
Transfer Hydrogenation ◽  
Allylic Alcohols ◽  
Selective Transfer ◽  
Unsaturated Aldehydes ◽  
Aldehydes And Ketones ◽  
Metal Catalyzed

This review describes the state-of-the-art of metal-catalyzed selective transfer hydrogenation of α,β-unsaturated aldehydes and ketones to the allylic alcohols, covering the literature of the last 30 years.

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