A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons

2017 ◽  
Vol 7 (20) ◽  
pp. 4580-4598 ◽  
Author(s):  
Haiyan Yang ◽  
Chen Zhang ◽  
Peng Gao ◽  
Hui Wang ◽  
Xiaopeng Li ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Hydrogenation ◽  
Value Added ◽  
Catalyst Design ◽  
Design Performance ◽  
Recent Developments ◽  
Hydrogenation Of Carbon Dioxide ◽  
Performance And Mechanism

We review the indirect and direct routes for CO2 hydrogenation to hydrocarbons and recent developments in catalyst design, performance and mechanism.

Catalytic Hydrogenation of Carbon Dioxide to Fuels

2014 ◽  
Vol 18 (10) ◽  
pp. 1335-1345 ◽  
Author(s):  
Xuecheng Yan ◽  
Han Guo ◽  
Dongjiang Yang ◽  
Shilun Qiu ◽  
Xiangdong Yao
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Hydrogenation ◽  
Hydrogenation Of Carbon Dioxide

scholarly journals Methanol Synthesis by Catalytic Hydrogenation of Carbon Dioxide on CuO-ZnO-Al2O3 Catalysts.

1995 ◽  
Vol 21 (3) ◽  
pp. 444-450 ◽  
Author(s):  
Tetsuya Imai ◽  
Kennosuke Kuroda ◽  
Masaki Hirano ◽  
Toru Akano
Keyword(s):  
Carbon Dioxide ◽  
Methanol Synthesis ◽  
Catalytic Hydrogenation ◽  
Hydrogenation Of Carbon Dioxide

scholarly journals Catalytic Hydrogenation of Carbon Dioxide on Group VIII Metals.

1993 ◽  
Vol 19 (5) ◽  
pp. 870-877 ◽  
Author(s):  
Hidehiro Iizuka ◽  
Shinichi Ichikawa ◽  
Eiji Ando ◽  
Ryoetsu Hase
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Hydrogenation ◽  
Group Viii ◽  
Hydrogenation Of Carbon Dioxide

Study on Ni Catalytic Hydrogenation of Carbon Dioxide for Methane

2014 ◽  
Vol 628 ◽  
pp. 16-19
Author(s):  
Long Zhou ◽  
Li Ping Ma ◽  
Ze Cheng Zi ◽  
Jun Ma ◽  
Jian Tao Chen
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Hydrogenation ◽  
Reduction Temperature ◽  
Carbon Dioxide Conversion ◽  
Methanation Reaction ◽  
Carbon Dioxide Methanation ◽  
Hydrogenation Of Carbon Dioxide ◽  
Optimal Reduction

Catalyst by different carriers prepared of carbon dioxide conversion sequence is: Ni/TiO2> Ni/γ-Al2O3> Ni/MgO > Ni/SiO2. Second metal, Co, Mn, Cu, La and Ce, was significantly enhanced the activity of methanation nickel-based catalysts in the carbon dioxide methanation reaction, but second metal of Cu was bad for the activity of methanation. The 10%Ni/Al2O3 and 2.5%Ce-10%Ni/Al2O3 catalysts were characterized by TG and H2-TPR，it was revealed to Ce which is benefit for reduce NiO reduction temperature and the optimal reduction temperature of the catalysts in between 400°C and 500 °C

scholarly journals Energy Densification of Biomass-Derived Furfurals to Furanic Biofuels by Catalytic Hydrogenation and Hydrodeoxygenation Reactions

2021 ◽  
Vol 2 (3) ◽  
pp. 521-549
Author(s):  
Nivedha Vinod ◽  
Saikat Dutta
Keyword(s):  
Catalytic Hydrogenation ◽  
Critical Discussion ◽  
Catalyst Design ◽  
Hydrogen Gas ◽  
Hydrogen Donor ◽  
Hydroxymethyl Furfural ◽  
Recent Developments ◽  
Potential Applications ◽  
Furanic Compounds

The concomitant hydrolysis and dehydration of biomass-derived cellulose and hemicellulose to furfural (FUR) and 5-(hydroxymethyl)furfural (HMF) under acid catalysis allows a dramatic reduction in the oxygen content of the parent sugar molecules with a 100% carbon economy. However, most applications of FUR or HMF necessitate synthetic modifications. Catalytic hydrogenation and hydrogenolysis have been recognized as efficient strategies for the selective deoxygenation and energy densification of biomass-derived furfurals generating water as the sole byproduct. Efficient and eco-friendly catalysts have been developed for the selective hydrogenation of furfurals affording renewable furanic compounds such as 2-methylfuran, 2,5-dimethylfuran and 2-methyltetrahydrofuran with potential applications as biofuel, solvent and chemical feedstock. Hydrogen gas or hydrogen donor molecules, required for the above processes, can also be renewably obtained from biomass using catalytic processes, enabling a circular economy. In this review, the recent developments in the energy densification of furfurals to furanic compounds of commercial significance are elaborated, emphasizing the role of catalyst and the reaction parameters employed. Critical discussion on sourcing hydrogen gas required for the processes, using hydrogen donor solvents, catalyst design and the potential markets of furanic intermediates have been made. Critical evaluations of the accomplishments and challenges in this field are also provided.

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