Catalytic Hydrogenation of Carbon Dioxide with a Highly Active Hydride on Ir(III)–Pincer Complex: Mechanism for CO2Insertion and Nature of Metal–Hydride Bond

2011 ◽  
Vol 84 (10) ◽  
pp. 1039-1048 ◽  
Author(s):  
Jun Li ◽  
Kazunari Yoshizawa
2014 ◽  
Vol 18 (10) ◽  
pp. 1335-1345 ◽  
Author(s):  
Xuecheng Yan ◽  
Han Guo ◽  
Dongjiang Yang ◽  
Shilun Qiu ◽  
Xiangdong Yao

1995 ◽  
Vol 21 (3) ◽  
pp. 444-450 ◽  
Author(s):  
Tetsuya Imai ◽  
Kennosuke Kuroda ◽  
Masaki Hirano ◽  
Toru Akano

2019 ◽  
Vol 7 (23) ◽  
pp. 14019-14026 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Sungho Yoon

A novel phenanthroline-functionalized porous organic polymer (phen-POP) has been designed, and prepared for the first time without other reactive functional groups in the polymer skeleton. Post-synthetic metalation of phen-POP with IrCl3 afforded a single-site, highly active and selective catalyst for the hydrogenation of CO2 to formate.


2020 ◽  
Vol 49 (9) ◽  
pp. 2994-3000
Author(s):  
Karan Chaudhary ◽  
Manoj Trivedi ◽  
D. T. Masram ◽  
Abhinav Kumar ◽  
Girijesh Kumar ◽  
...  

Catalytic conversion of CO2via hydrogenation using in situ gaseous H2 (granulated tin metal and concentrated HCl) to produce the formate salt (HCO2−) with turnover number (TON) values of 326 to 1.065 × 105 in 12 h to 48 h of reaction at 25 °C to 80 °C has been reported.


1993 ◽  
Vol 19 (5) ◽  
pp. 870-877 ◽  
Author(s):  
Hidehiro Iizuka ◽  
Shinichi Ichikawa ◽  
Eiji Ando ◽  
Ryoetsu Hase

2016 ◽  
Vol 89 (1) ◽  
pp. 113-124 ◽  
Author(s):  
Wataru Aoki ◽  
Natdanai Wattanavinin ◽  
Shuhei Kusumoto ◽  
Kyoko Nozaki

2014 ◽  
Vol 628 ◽  
pp. 16-19
Author(s):  
Long Zhou ◽  
Li Ping Ma ◽  
Ze Cheng Zi ◽  
Jun Ma ◽  
Jian Tao Chen

Catalyst by different carriers prepared of carbon dioxide conversion sequence is: Ni/TiO2> Ni/γ-Al2O3> Ni/MgO > Ni/SiO2. Second metal, Co, Mn, Cu, La and Ce, was significantly enhanced the activity of methanation nickel-based catalysts in the carbon dioxide methanation reaction, but second metal of Cu was bad for the activity of methanation. The 10%Ni/Al2O3 and 2.5%Ce-10%Ni/Al2O3 catalysts were characterized by TG and H2-TPR,it was revealed to Ce which is benefit for reduce NiO reduction temperature and the optimal reduction temperature of the catalysts in between 400°C and 500 °C


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