Enhanced thermal stability of palladium oxidation catalysts using phosphate-modified alumina supports

2017 ◽  
Vol 7 (21) ◽  
pp. 5038-5048 ◽  
Author(s):  
Jinshi Dong ◽  
Jun Wang ◽  
Jianqiang Wang ◽  
Ming Yang ◽  
Wei Li ◽  
...  

Alumina with 5.0 μmol m−2 phosphorus additives could retain a higher Pd dispersion after aging, resulting in much higher CO oxidation activity.

2020 ◽  
Vol 10 (3) ◽  
pp. 625-629
Author(s):  
Behzad Tangeysh ◽  
Clarke Palmer ◽  
Horia Metiu ◽  
Michael J. Gordon ◽  
Eric W. McFarland

Suspensions of platinum nanoparticles (PtNPs) were formed in molten LiCl–LiBr–KBr via thermal decomposition of H2PtCl6, and subsequently evaluated for thermal stability and CO oxidation activity.


2020 ◽  
Author(s):  
O. S. Bezkrovnyi ◽  
P. Kraszkiewicz ◽  
W. Mista ◽  
L. Kepinski

Abstract The thermal stability of Au nanoparticles on ceria support of various morphology (nanocubes, nanooctahedra, and {111}-nanofacetted nanocubes) in oxidizing and reducing atmospheres was investigated by electron microscopy. A beneficial effect of the reconstruction of edges of ceria nanocubes into zigzagged {111}-nanofacetted structures on the inhibition of sintering of Au nanoparticles was shown. The influence of different morphology of Au particles on various ceria supports on the reducibility and catalytic activity in CO oxidation, and CO PROX of Au/ceria catalysts was also investigated and discussed. It was shown, that ceria nanocubes with flat {110} terminated edges are more suitable as a support for Au nanoparticles, used to catalyze CO oxidation, than zigzagged {111}- nanofacetted structures. Graphic Abstract


2008 ◽  
Vol 78 (11) ◽  
pp. 2214-2219 ◽  
Author(s):  
S. A. Trifonov ◽  
A. A. Malygin ◽  
A. K. D’yakova ◽  
J. -M. Lopez-Cuesta ◽  
N. Cinausero

2017 ◽  
Vol 60 (12-14) ◽  
pp. 898-913 ◽  
Author(s):  
T. Yu Kardash ◽  
E. M. Slavinskaya ◽  
R. V. Gulyaev ◽  
A. V. Zaikovskii ◽  
S. A. Novopashin ◽  
...  

2018 ◽  
Vol 8 (5) ◽  
pp. 1383-1394 ◽  
Author(s):  
Iljeong Heo ◽  
Steven J. Schmieg ◽  
Se H. Oh ◽  
Wei Li ◽  
Charles H. F. Peden ◽  
...  

CuO supported on a commercial mixed cerium–zirconium oxide shows remarkable improvement in CO oxidation after high temperature hydrothermal aging.


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