Structure and reactivity of [RuII(terpy)(N^N)Cl]Cl complexes: consequences for biological applications

2017 ◽  
Vol 46 (31) ◽  
pp. 10264-10280 ◽  
Author(s):  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Olga Impert ◽  
Anna Kozakiewicz ◽  
Andrzej Surdykowski ◽  
...  
Keyword(s):  
Ligand Substitution ◽  
Biological Applications ◽  
Substitution Reactions ◽  
Aqua Complexes ◽  
Solution Structures ◽  
High Chloride ◽  
Chloride Concentrations ◽  
Ligand Substitution Reactions

Ligand substitution reactions of [RuII(terpy)(N^N)Cl]Cl, where N^N = bipy and en, and the corresponding aqua complexes were studied in detail, including the crystal and solution structures of the chlorido complexes. The chlorido complex undergoes spontaneous aquation that can only be prevented using high chloride concentrations (>2 M).

scholarly journals Physical properties, ligand substitution reactions, and biological activity of Co(iii)-Schiff base complexes

2019 ◽  
Vol 48 (18) ◽  
pp. 5987-6002 ◽  
Author(s):  
A. Paden King ◽  
Hendryck A. Gellineau ◽  
Samantha N. MacMillan ◽  
Justin J. Wilson
Keyword(s):  
Biological Activity ◽  
Schiff Base ◽  
Physical Properties ◽  
Ligand Exchange ◽  
Ligand Substitution ◽  
Schiff Base Complexes ◽  
Substitution Reactions ◽  
Anticancer Properties ◽  
Ligand Substitution Reactions

A subset of fluorinated Co(iii) Schiff base complexes was synthesized, and their structural, ligand exchange, and anticancer properties were investigated.

Dinuclear nitrido-bridged ruthenium complexes bearing diimine ligands

2017 ◽  
Vol 46 (41) ◽  
pp. 14256-14263 ◽  
Author(s):  
Julie Urgiles ◽  
Sarah R. Nathan ◽  
Samantha N. MacMillan ◽  
Justin J. Wilson
Keyword(s):  
Calcium Uptake ◽  
Ruthenium Complexes ◽  
Ligand Substitution ◽  
Mitochondrial Calcium ◽  
Substitution Reactions ◽  
Uptake Inhibition ◽  
Diimine Ligands ◽  
Mitochondrial Calcium Uptake ◽  
Ligand Substitution Reactions

Nitrido-bridged ruthenium complexes are synthesized via ligand substitution reactions and evaluated for mitochondrial calcium uptake inhibition.

Axial ligand substitution reactions of iron(II) phthalocyanine adducts

1980 ◽  
Vol 19 (7) ◽  
pp. 2162-2165 ◽  
Author(s):  
Jens Martinsen ◽  
Michael Miller ◽  
Daria Trojan ◽  
D. A. Sweigart
Keyword(s):  
Ligand Substitution ◽  
Axial Ligand ◽  
Substitution Reactions ◽  
Ligand Substitution Reactions
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