Benzene-centred tripodal diglycolamides for the sequestration of trivalent actinides: metal ion extraction and luminescence spectroscopic investigations in a room temperature ionic liquid

Abstract This review article gives a comprehensive account of the extraction of actinide ions using room temperature ionic liquid-based solvent systems containing diglycolamide (DGA) or functionalized DGA extractants. These extractants include multiple DGA-functionalized ligands such as tripodal DGA (T-DGA) and DGA-functionalized calix [4]arenes (C4DGA). Apart from metal ion extraction behaviour, other important features of the ionic liquid-based solvent systems such as separation behaviour, luminescence spectroscopic results, thermodynamics of extraction and radiolytic stability of the ionic liquid-based solvents are also reviewed. Results from studies on DGA-functionalized task-specific ionic liquids (TSIL) are also included in this review article.

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ChemInform Abstract: The Direct Substitutions of 9H-Xanthen-9-ol with Indoles in a Room-Temperature Ionic Liquid Medium BmimBF4.

ChemInform ◽

10.1002/chin.201204127 ◽

2011 ◽

Vol 43 (4) ◽

pp. no-no

Author(s):

Ling-yan Liu ◽

Bing Wang ◽

Hong-mei Yang ◽

Wei-xing Chang ◽

Jing Li

Keyword(s):

Ionic Liquid ◽

Liquid Medium ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Ionic Liquid Medium

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Ag3PO4/BiPO4 p–n heterojunction nanocomposite prepared in room-temperature ionic liquid medium with improved photocatalytic activity

Materials Science in Semiconductor Processing ◽

10.1016/j.mssp.2015.05.066 ◽

2015 ◽

Vol 39 ◽

pp. 506-514 ◽

Cited By ~ 38

Author(s):

N. Mohaghegh ◽

E. Rahimi ◽

M.R. Gholami

Keyword(s):

Ionic Liquid ◽

Photocatalytic Activity ◽

Liquid Medium ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Ionic Liquid Medium

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Enzyme-free selective determination of H2O2 and glucose using functionalized CuNP-modified graphite electrode in room temperature ionic liquid medium

RSC Advances ◽

10.1039/c4ra04507f ◽

2014 ◽

Vol 4 (88) ◽

pp. 47497-47504 ◽

Cited By ~ 13

Author(s):

Rajendran Suresh Babu ◽

Pandurangan Prabhu ◽

Sangilimuthu Sriman Narayanan

Keyword(s):

Ionic Liquid ◽

Liquid Medium ◽

Modified Electrode ◽

Room Temperature ◽

Graphite Electrode ◽

Room Temperature Ionic Liquid ◽

Selective Determination ◽

Highly Sensitive ◽

Ionic Liquid Medium

The proposed method demonstrates a new PCFCuNP modified electrode using ionic liquid as a green electrolyte. This method also achieved highly sensitive and selective determination towards H2O2 and glucose.

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A rapid synthetic method for organic polymer-based monoliths in a room temperature ionic liquid medium via microwave-assisted vinylization and polymerization

Green Chemistry ◽

10.1039/c0gc00803f ◽

2011 ◽

Vol 13 (2) ◽

pp. 296-299 ◽

Cited By ~ 38

Author(s):

Yung-Han Shih ◽

Brenda Singco ◽

Wan-Ling Liu ◽

Chao-Hsiang Hsu ◽

Hsi-Ya Huang

Keyword(s):

Ionic Liquid ◽

Liquid Medium ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Organic Polymer ◽

Synthetic Method ◽

Microwave Assisted ◽

Ionic Liquid Medium

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The direct substitutions of 9H-xanthen-9-ol with indoles in a room temperature ionic liquid medium BmimBF4

Tetrahedron Letters ◽

10.1016/j.tetlet.2011.08.085 ◽

2011 ◽

Vol 52 (43) ◽

pp. 5636-5639 ◽

Cited By ~ 13

Author(s):

Ling-yan Liu ◽

Bing Wang ◽

Hong-mei Yang ◽

Wei-xing Chang ◽

Jing Li

Keyword(s):

Ionic Liquid ◽

Liquid Medium ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Ionic Liquid Medium

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Precipitation of a Dioxouranium(VI) Species from a Room Temperature Ionic Liquid Medium

Inorganic Chemistry ◽

10.1021/ic015619w ◽

2002 ◽

Vol 41 (7) ◽

pp. 1692-1694 ◽

Cited By ~ 53

Author(s):

Antonia E. Bradley ◽

Justine E. Hatter ◽

Mark Nieuwenhuyzen ◽

William R. Pitner ◽

Kenneth R. Seddon ◽

...

Keyword(s):

Ionic Liquid ◽

Liquid Medium ◽

Room Temperature ◽

Room Temperature Ionic Liquid ◽

Ionic Liquid Medium

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Complexation of tetraalkyl diglycolamides with trivalent f-cations in a room temperature ionic liquid: extraction and spectroscopic investigations

Dalton Transactions ◽

10.1039/c7dt01090g ◽

2017 ◽

Vol 46 (23) ◽

pp. 7584-7593 ◽

Cited By ~ 8

Author(s):

Seraj Ahmad Ansari ◽

Rajesh Bhikaji Gujar ◽

Prasanta Kumar Mohapatra

Keyword(s):

Ionic Liquid ◽

Room Temperature ◽

Liquid Extraction ◽

Room Temperature Ionic Liquid ◽

Spectroscopic Investigations

This paper reports the complexation of a series of tetraalkyl diglycolamides (TRDGA) with trivalent f-cations in a room temperature ionic liquid,viz. 3-octyl-1-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C8mim][Tf2N]).

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