Pd-PEPPSI-IPentCl: a new highly efficient ligand-free and recyclable catalyst system for the synthesis of 2-substituted indoles via domino copper-free Sonogashira coupling/cyclization

2017 ◽  
Vol 41 (16) ◽  
pp. 8187-8195 ◽  
Author(s):  
Murali Krishna Kolli ◽  
Nagul Meera Shaik ◽  
Govindasamy Chandrasekar ◽  
Sridhar Chidara ◽  
Raghu Babu Korupolu

One pot synthesis of 2-substituted indolesviaSonogashira coupling (without a copper catalyst) followed by intermolecular cyclization using Pd-PEPPSI-IPentCl.

2019 ◽  
Vol 17 (17) ◽  
pp. 4281-4290 ◽  
Author(s):  
Hitesh Kumar Saini ◽  
Shiv Dhiman ◽  
Nitesh Kumar Nandwana ◽  
Rangan Krishnan ◽  
Anil Kumar

A highly efficient protocol has been developed for the synthesis of diversely substituted isoindolo[2,1-b]isoquinolin-7(5H)-ones through sequential Cu(ii)-catalyzed Sonogashira coupling, intramolecular hydroamidation followed by palladium-catalyzed ligand free Heck reaction.


2017 ◽  
Vol 15 (33) ◽  
pp. 6997-7007 ◽  
Author(s):  
Anirban Kayet ◽  
Vinod K. Singh

Pd(ii)–Ag(i) catalysed, highly efficient synthesis of diindolylmethanes under mild reaction conditions, with six new bonds being formed in a one-pot fashion, and the products being transformed into synthetically useful compounds.


2020 ◽  
Vol 44 (20) ◽  
pp. 8614-8620 ◽  
Author(s):  
Song-Tao Xiao ◽  
Cui-Ting Ma ◽  
Jia-Qi Di ◽  
Zhan-Hui Zhang

An approach was developed for the synthesis of 2,4-disubstituted quinoline derivatives via a one pot three-component reaction of aromatic amines, aldehydes and alkynes catalyzed by MOF-5 under solvent-free conditions.


RSC Advances ◽  
2015 ◽  
Vol 5 (37) ◽  
pp. 28857-28863 ◽  
Author(s):  
Ya-Qin Yu ◽  
Da-Zhen Xu

A recyclable catalyst for one-pot synthesis of β-phosphonomalonates via tandem Knoevenagel–phospha-Michael reaction.


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