1,3-Disulfoimidazolium chloronickellate immobilized HZSM-5 framework as visible-light-induced heterogeneous photocatalyst for advanced oxidation process

2018 ◽  
Vol 42 (5) ◽  
pp. 3867-3877 ◽  
Author(s):  
Susmita Saikia ◽  
Pinky Gogoi ◽  
Ruli Borah

Hybrid photocatalysts of [Dsim]2[NiCl4]/HZSM-5 were prepared by wet impregnation and their application is demonstrated as feasible heterogeneous photocatalysts for oxidative degradation of methylene blue under sunlight.

2018 ◽  
Vol 4 (10) ◽  
pp. 1389-1411 ◽  
Author(s):  
Moses G. Peleyeju ◽  
Omotayo A. Arotiba

Electrochemical advanced oxidation process and heterogeneous photocatalysis have received great attention in the last few years as alternative/complementary water treatment technologies.


2014 ◽  
Vol 279 ◽  
pp. 105-110 ◽  
Author(s):  
Byung-Taek Oh ◽  
Young-Suk Seo ◽  
Dega Sudhakar ◽  
Ji-Hyun Choe ◽  
Sang-Myeong Lee ◽  
...  

2016 ◽  
Vol 688 ◽  
pp. 703-711 ◽  
Author(s):  
Wenjuan Li ◽  
Ze Wang ◽  
Defen Kong ◽  
Dandan Du ◽  
Min Zhou ◽  
...  

2016 ◽  
Vol 42 (9) ◽  
pp. 10892-10901 ◽  
Author(s):  
Ritu Malik ◽  
Vandna Chaudhary ◽  
Vijay K. Tomer ◽  
Pawan S. Rana ◽  
S.P. Nehra ◽  
...  

Author(s):  
Liang Sun ◽  
Dehao Hu ◽  
Ziyu Zhang ◽  
Xiaoyan Deng

H2O2- and PDS-based reactions are two typical advanced oxidation processes (AOPs). In this paper, a comparative study of H2O2/PDS-based AOPs employing natural pyrite as a catalyst to degrade methylene blue (MB) was reported. The adaptive pH range in pyrite/PDS extended from 3 to 11, in contrast to the narrow effective pH range of 3–7 in pyrite/H2O2. As a result of the iron leaching, a synergistic effect of both homogeneous and heterogeneous catalysis was observed in pyrite/PDS, whereas heterogeneous catalytic oxidation dominated pyrite/H2O2. Furthermore, the batch results showed that the MB removal by pyrite/PDS was highly dependent on chemical conditions (e.g., pH, pyrite and PDS concentration, temperature). Powerful SO4•− was generated by pyrite rapidly under acidic or weakly acidic conditions, while SO4•− and PDS were assumed by OH− under alkaline condition. The lower pyrite loading (from 0.1 to 0.5 g/L) was affected the removal efficiency obviously, while the scavenging of SO4•− did not seem to be remarkable with the excessive amounts of pyrite (>0.5 g/L). Excessive amounts of PDS (>2 mmol/L) might negatively affect the pyrite/PDS system. The reaction temperature that increased from 20 to 40 °C had a positive effect on the degradation of MB. SEM and XRD showed that the passivation of catalyst did not occur due to the strong acid-production ability of pyrite/PDS, inhibiting the formation of Fe-oxide covering the pyrite surface.


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