scholarly journals Self-sacrificed two-dimensional REO(CH3COO) template-assisted synthesis of ultrathin rare earth oxide nanoplates

2017 ◽  
Vol 4 (7) ◽  
pp. 1182-1186 ◽  
Author(s):  
Rui Liu ◽  
Ke Wu ◽  
Lin-Dong Li ◽  
Ling-Dong Sun ◽  
Chun-Hua Yan

Ultrathin RE2O3nanoplates are synthesized by a hot-injection methodviathein situformed REO(CH3COO) template.

Catalysts ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 328 ◽  
Author(s):  
Ning Dong ◽  
Qing Ye ◽  
Mengyue Chen ◽  
Shuiyuan Cheng ◽  
Tianfang Kang ◽  
...  

The sodium-treated sepiolite (NaSep)-supported rare earth oxide (RE/NaSep; RE = La, Eu, Dy, and Tm) samples were prepared using the rotary evaporation method. Physicochemical properties of these materials were characterized by XRD, SEM, BET, FTIR, XPS, H2–TPR, NH3–TPD, and in situ DRIFTS, and their catalytic activities for formaldehyde (HCHO) (2000 ppm) oxidation were evaluated. The results show that loading of the rare earth oxide on NaSep improved its catalytic performance. Among all the samples, Eu/NaSep performed the best, and complete HCHO conversion was achieved at a temperature of 150 °C and a gas hourly space velocity of 240,000 mL/(g h); a good catalytic activity was still maintained after 45 h of stability test. The catalytic oxidation mechanism of HCHO was studied using the in situ DRIFTS technique. As a result, the effective and stable catalytic performance of the Eu/NaSep sample was mainly due to the presence of hydroxyl groups on the sepiolite surface and the doped rare earth oxides, which contributed to its high performance. HCHO oxidation underwent via the steps of HCHO + O2 → HCOO− + OH− → H2O + CO2. It is concluded that the optimal catalytic activity of Eu/NaSep was associated with the highest Oads/Olatt atomic ratio, the largest amount of hydroxyl groups, the highest acidity, and the best reducibility. The present work may provide new insights into the application in the removal of high-concentration HCHO over the rare earth oxides supported on natural low-cost clays.


2009 ◽  
Vol 27 (6) ◽  
pp. 997-1002 ◽  
Author(s):  
Chaofeng WU ◽  
Mingxing MA ◽  
Wenjin LIU ◽  
Minlin ZHONG ◽  
Hongjun ZHANG ◽  
...  

2009 ◽  
Vol 82 (9) ◽  
pp. 1197-1202 ◽  
Author(s):  
Masahiro Itoh ◽  
Koji Motoki ◽  
Makoto Saito ◽  
Jun Iwamoto ◽  
Ken-ichi Machida

2011 ◽  
Vol 286 (1-2) ◽  
pp. 32-47 ◽  
Author(s):  
Christopher M. Fisher ◽  
John M. Hanchar ◽  
Scott D. Samson ◽  
Bruno Dhuime ◽  
Janne Blichert-Toft ◽  
...  

2021 ◽  
Author(s):  
Yijuan Wang ◽  
Jianzhi Wang ◽  
Jie Liu ◽  
Zhuangwei Xiao ◽  
Yanan Xue ◽  
...  

A rigid segment-containing polysulfide was used as a sulfur source and in situ intercalator to induce the formation of few-layer and 1T-rich MoS2.


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