scholarly journals A high-temperature organic–inorganic ferroelectric with outstanding switchable dielectric characteristics

RSC Advances ◽  
2017 ◽  
Vol 7 (76) ◽  
pp. 47933-47937 ◽  
Author(s):  
Cong Xu ◽  
Wenjun Zhang ◽  
Linsong Gao ◽  
Xuecheng Gan ◽  
Xiaofan Sun ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase ◽  
Hybrid Compound ◽  
Dielectric Characteristics ◽  
Inorganic Hybrid ◽  
Compound C

A new molecular ferroelectric is discovered in an organic–inorganic hybrid compound, (C6H5NH3)2CdCl4, which undergoes a reversible order–disorder ferroelectric phase transition at 369 K.

Synthesis and characterization of a new organic–inorganic hybrid ferroelectric: (C4H10N)6[InBr6][InBr4]3·H2O

2019 ◽  
Vol 48 (46) ◽  
pp. 17402-17407 ◽  
Author(s):  
Wen-Bo Xin ◽  
Guan-Cheng Xu ◽  
Min Li
Keyword(s):  
Phase Transition ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase ◽  
Order Transition ◽  
Synthesis And Characterization ◽  
Inorganic Hybrid ◽  
Compound C

Compound (C4H10N)6[InBr6][InBr4]3·H2O undergoes a paraelectric–ferroelectric phase transition at 232 K, which triggered by the disorder–order transition of Br atoms in [InBr4]− anions.

Ferroelectric Properties in Organic-inorganic Hybrid Material Tris(2-Hydroxyethyl) ammonium Trichloro Cadmium(Ⅱ)

2022 ◽  
Author(s):  
Zheng Tang ◽  
Xiaofan Sun ◽  
Zhangran Gao ◽  
Dong Li ◽  
Shulin Jiao ◽  
...  
Keyword(s):  
Phase Transition ◽  
Aqueous Solution ◽  
Hybrid Material ◽  
Ferroelectric Phase Transition ◽  
Room Temperature ◽  
Ferroelectric Phase ◽  
Ferroelectric Properties ◽  
Inorganic Hybrid ◽  
Space Group ◽  
Inorganic Hybrid Material

Organic-inorganic hybrid ferroelectric Tris(2-Hydroxyethyl) ammonium trichloro cadmium(Ⅱ) (TATC) with a space group of P21/c at room temperature was obtained in aqueous solution. There goes a paraelectric-ferroelectric phase transition (from monoclinic...

High-temperature ferroelectric phase transition observed in multiferroic Bi0.91La0.05Tb0.04FeO3

2009 ◽  
Vol 95 (1) ◽  
pp. 012909 ◽  
Author(s):  
Q. H. Jiang ◽  
F. T. Liu ◽  
Ce-Wen Nan ◽  
Yuan-Hua Lin ◽  
M. J. Reece ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase

The first high-temperature multiaxial ferroelectric host–guest inclusion compound

2019 ◽  
Vol 55 (77) ◽  
pp. 11571-11574 ◽  
Author(s):  
Han-Yue Zhang ◽  
Si-Qi Lu ◽  
Xin Chen ◽  
Ren-Gen Xiong ◽  
Yuan-Yuan Tang
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Ferroelectric Phase Transition ◽  
Inclusion Compound ◽  
Ferroelectric Phase

A host–guest inclusion compound, 18-crown-6 oxonium tetrachloride-gallium(iii), was shown to undergo a 4/mmmFmm2-type ferroelectric phase transition with four crystallographically equivalent polarization directions at 337 K.

scholarly journals Low-frequency Raman study of the ferroelectric phase transition in a layeredCuCl4-based organic-inorganic hybrid

2014 ◽  
Vol 89 (2) ◽  
Author(s):  
Antonio Caretta ◽  
Rany Miranti ◽  
Remco W. A. Havenith ◽  
Elia Rampi ◽  
Michiel C. Donker ◽  
...  
Keyword(s):  
Phase Transition ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase ◽  
Low Frequency ◽  
Inorganic Hybrid ◽  
Raman Study

Dielectric characteristics and diffuse ferroelectric phase transition in Sr4La2Ti4Nb6O30 tungsten bronze ceramics

2006 ◽  
Vol 21 (7) ◽  
pp. 1787-1792 ◽  
Author(s):  
X.L. Zhu ◽  
X.M. Chen ◽  
X.Q. Liu ◽  
Y. Yuan
Keyword(s):  
Phase Transition ◽  
Dielectric Constant ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase ◽  
Tungsten Bronze ◽  
Frequency Dispersion ◽  
Dielectric Characteristics ◽  
Low Dielectric ◽  
Dielectric Data ◽  
Maximum Dielectric Constant

In this work, Sr4La2Ti4Nb6O30 ceramics with tetragonal filled tungsten bronze structure were prepared, and the dielectric characteristics and ferroelectric transition were investigated. The room-temperature dielectric constant of the present ceramics showed very weak frequency dependency; it decreased from 570.4 to 561.7 when the frequency varied from 200 Hz to 1 MHz, and a comparatively low-dielectric loss was observed (in the order of 10−3). Unlike the situation for Ba4Ln2Ti4Nb6O30 (Ln = La, Nd and Sm), Sr4La2Ti4Nb6O30 ceramics showed a diffuse ferroelectric phase transition, and the diffuseness exponent γ was 1.61. Moreover, the obvious frequency dispersion was observed over a broad frequency range from 200 Hz to 1 MHz, and the maximum dielectric constant temperature Tmax shifted to higher temperatures with increasing frequency. The dielectric data agreed closely with the Vogel–Fulcher relationship. We concluded that tungsten bronze Sr4La2Ti4Nb6O30 has the relaxor ferroelectric nature.

Sign in / Sign up

Export Citation Format

Share Document