scholarly journals A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides

2017 ◽  
Vol 8 (5) ◽  
pp. 3660-3667 ◽  
Author(s):  
Olaf Cussó ◽  
Michael W. Giuliano ◽  
Xavi Ribas ◽  
Scott J. Miller ◽  
Miquel Costas
Keyword(s):  
Hydrogen Peroxide ◽  
Coordination Complexes ◽  
Asymmetric Epoxidation ◽  
Coordination Complex ◽  
High Yield ◽  
Aqueous Hydrogen Peroxide ◽  
Bottom Up ◽  
Iron Coordination

The combination of peptides and a chiral iron coordination complex catalyzes high yield highly asymmetric epoxidation with aqueous hydrogen peroxide.

Asymmetric epoxidation of olefins catalyzed by Ti(salan) complexes using aqueous hydrogen peroxide as the oxidant

2008 ◽  
Vol 80 (5) ◽  
pp. 1071-1077 ◽  
Author(s):  
Kazuhiro Matsumoto ◽  
Yuji Sawada ◽  
Tsutomu Katsuki
Keyword(s):  
Hydrogen Peroxide ◽  
Phosphate Buffer ◽  
Asymmetric Epoxidation ◽  
High Yield ◽  
Aqueous Hydrogen Peroxide ◽  
Isolation And Purification ◽  
Epoxidation Of Olefins

Ti(salan) complexes were found to be efficient catalysts for asymmetric epoxidation with aqueous hydrogen peroxide as the oxidant. In the presence of pH 7.4 phosphate buffer, the reaction of various conjugate olefins proceeded smoothly to afford the corresponding epoxides in high yield with high enantioselectivity, even on a multigram scale. Ti(salan) complexes could be prepared from Ti(OiPr)4 and the corresponding salan ligand and directly used without isolation and purification.

Titanium–Salan-Catalyzed Asymmetric Epoxidation with Aqueous Hydrogen Peroxide as the Oxidant

2006 ◽  
Vol 118 (21) ◽  
pp. 3558-3560 ◽  
Author(s):  
Yuji Sawada ◽  
Kazuhiro Matsumoto ◽  
Shoichi Kondo ◽  
Hisayuki Watanabe ◽  
Tomoyuki Ozawa ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Asymmetric Epoxidation ◽  
Aqueous Hydrogen Peroxide

Asymmetric Epoxidation with Aqueous Hydrogen Peroxide as the Oxidant

Synfacts ◽  
2006 ◽  
Vol 2006 (8) ◽  
pp. 0804-0804
Author(s):  
T. Katsuki ◽  
Y. Sawada ◽  
K. Matsumoto ◽  
S. Kondo ◽  
H. Watanabe ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Asymmetric Epoxidation ◽  
Aqueous Hydrogen Peroxide

A Simple and Efficient Preparation of Penicillin V β-Sulfoxide

1986 ◽  
Vol 39 (7) ◽  
pp. 1165 ◽  
Author(s):  
M Davis ◽  
WY Wu
Keyword(s):  
Hydrogen Peroxide ◽  
High Yield ◽  
Aqueous Hydrogen Peroxide ◽  
Two Phase ◽  
Penicillin V ◽  
Phase Mixture

Penicillin V (1) can be oxidized to the β- sulfoxide (2) in high yield in a two-phase mixture of dichloromethane and aqueous hydrogen peroxide. The addition of acids or metallic catalysts is not necessary.

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