scholarly journals Design of electric field controlled molecular gates mounted on metal–organic frameworks

2017 ◽  
Vol 5 (18) ◽  
pp. 8690-8696 ◽  
Author(s):  
Benjamin Tam ◽  
Ozgur Yazaydin
Keyword(s):  
Electric Field ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Molecular Gates ◽  
And Control ◽  
Control Diffusion

Molecular gates mounted on MOFs act like nanovalves and control diffusion of molecules.

Structural defects in metal–organic frameworks (MOFs): Formation, detection and control towards practices of interests

2017 ◽  
Vol 349 ◽  
pp. 169-197 ◽  
Author(s):  
Jianwei Ren ◽  
Mpho Ledwaba ◽  
Nicholas M. Musyoka ◽  
Henrietta W. Langmi ◽  
Mkhulu Mathe ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Defects ◽  
Metal Organic ◽  
And Control

scholarly journals Electrically Enhanced Hydrogen Adsorption in Metal-Organic Frameworks

2019 ◽  
Author(s):  
Liviu Zarbo ◽  
Marius Oancea ◽  
Emmanuel Klontzas ◽  
Emmanuel Tylianakis ◽  
Ioana G. Grosu ◽  
...  
Keyword(s):  
Electric Field ◽  
Hydrogen Storage ◽  
Applied Electric Field ◽  
Hydrogen Adsorption ◽  
Metal Organic Frameworks ◽  
Hydrogen Uptake ◽  
Multiscale Approach ◽  
Hydrogen Storage Materials ◽  
Metal Organic ◽  
Electrically Enhanced

<p>Using a multiscale approach, we show that applied electric field does not affect significantly the hydrogen uptake of weakly polarizable metal-organic frameworks (MOFs). Nonetheless, we show that, for large MOF polarizabilities, the hydrogen uptake can double in applied electric field. We propose searching for a novel class of hydrogen storage materials, that of highly polarizable porous MOFs. Hydrogen uptake in such materials would be controlled by electric field, a much easier to adjust parameter than pressure or temperature.</p>

scholarly journals Electric field induced rotation of halogenated organic linkers in isoreticular metal–organic frameworks for nanofluidic applications

2018 ◽  
Vol 3 (6) ◽  
pp. 951-958 ◽  
Author(s):  
Sadanandam Namsani ◽  
A. Ozgur Yazaydin
Keyword(s):  
Electric Field ◽  
Metal Organic Frameworks ◽  
Metal Organic

Electric field induced rotation of IRMOF linkers provides opportunities for controlling the diffusion of molecules for nanofluidic applications.

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