Oxidative coupling of enolates using memory of chirality: an original enantioselective synthesis of quaternary α-amino acid derivatives

2018 ◽  
Vol 54 (90) ◽  
pp. 12742-12745
Author(s):  
Antonin Mambrini ◽  
Didier Gori ◽  
Régis Guillot ◽  
Cyrille Kouklovsky ◽  
Valérie Alezra
Keyword(s):  
Amino Acid ◽  
Oxidative Coupling ◽  
Enantioselective Synthesis ◽  
Amino Acid Derivatives ◽  
Memory Of Chirality

A memory of chirality strategy allowed the first enantioselective oxidative heterocoupling of enolates.

An enantioselective synthesis of β2-amino acid derivatives

2005 ◽  
Vol 16 (7) ◽  
pp. 1309-1319 ◽  
Author(s):  
Jomana Elaridi ◽  
Ali Thaqi ◽  
Andrew Prosser ◽  
W. Roy Jackson ◽  
Andrea J. Robinson
Keyword(s):  
Amino Acid ◽  
Enantioselective Synthesis ◽  
Amino Acid Derivatives

scholarly journals Memory of Chirality in Alkylation of a-Amino Acid Derivatives

2000 ◽  
Author(s):  
Takeo Kawabata ◽  
Hideo Suzuki ◽  
Yoshikazu Nagae ◽  
Thomas Wirth ◽  
Kyoshi Yahiro ◽  
...  
Keyword(s):  
Amino Acid ◽  
Amino Acid Derivatives ◽  
Memory Of Chirality

scholarly journals Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions

2016 ◽  
Vol 7 (2) ◽  
pp. 1104-1108 ◽  
Author(s):  
Jun-Xia Guo ◽  
Ting Zhou ◽  
Bin Xu ◽  
Shou-Fei Zhu ◽  
Qi-Lin Zhou
Keyword(s):  
Amino Acids ◽  
Amino Acid ◽  
Enantioselective Synthesis ◽  
Insertion Reaction ◽  
Amino Acid Derivatives ◽  
Insertion Reactions ◽  
Phosphoric Acids

A new highly enantioselective route to α-alkenyl α-amino acid derivatives using a N–H insertion reaction of vinyldiazoacetates and tert-butyl carbamate cooperatively catalyzed by achiral dirhodium(ii) carboxylates and chiral spiro phosphoric acids was developed.

Asymmetric Carbonyl Migration of α-Amino Acid Derivatives via Memory of Chirality

Synlett ◽  
2011 ◽  
Vol 2011 (04) ◽  
pp. 543-546 ◽  
Author(s):  
Takeo Kawabata ◽  
Fumiteru Teraoka ◽  
Kaoru Fuji ◽  
Orhan Ozturk ◽  
Tomoyuki Yoshimura
Keyword(s):  
Amino Acid ◽  
Amino Acid Derivatives ◽  
Memory Of Chirality
Sign in / Sign up

Export Citation Format

Share Document