Silyl–pyridine–amine pincer-ligated iridium complexes for catalytic silane deuteration via room temperature C–D bond activation of benzene-d6

2019 ◽  
Vol 55 (7) ◽  
pp. 957-960 ◽  
Author(s):  
Takashi Komuro ◽  
Tomohiro Osawa ◽  
Ryuju Suzuki ◽  
Daiki Mochizuki ◽  
Hironori Higashi ◽  
...  
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Iridium Complexes

SiNN-pincer iridium complexes were synthesised and demonstrated to catalyse deuteration of trialkylsilanes with benzene-d6 through H/D exchange at room temperature.

Room-Temperature Selective Aliphatic Carbon–Carbon Bond Activation and Functionalization of Ethers by Rhodium(II) Porphyrin

2011 ◽  
Vol 30 (14) ◽  
pp. 3691-3693 ◽  
Author(s):  
Siu Yin Lee ◽  
Tsz Ho Lai ◽  
Kwong Shing Choi ◽  
Kin Shing Chan
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Aliphatic Carbon

scholarly journals Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

2016 ◽  
Vol 52 (88) ◽  
pp. 12960-12963 ◽  
Author(s):  
Andrea Monas ◽  
Krunoslav Užarević ◽  
Ivan Halasz ◽  
Marina Juribašić Kulcsár ◽  
Manda Ćurić
Keyword(s):  
Methyl Orange ◽  
Solid State ◽  
Room Temperature ◽  
Bond Activation ◽  
Aqueous Media ◽  
Accelerated Aging ◽  
Water Soluble ◽  
Clean Synthesis

Room-temperature accelerated aging in the solid state has been applied for quantitative azobenzene C–H bond activation by Pd(OAc)2. Water-soluble dicyclopalladated methyl orange is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in aqueous media.

A coordinatively unsaturated iridium complex with an unsymmetrical redox-active ligand: (spectro)electrochemical and reactivity studies

2019 ◽  
Vol 48 (37) ◽  
pp. 13931-13942 ◽  
Author(s):  
Sebastian Sobottka ◽  
Margarethe Behr van der Meer ◽  
Estelle Glais ◽  
Uta Albold ◽  
Simon Suhr ◽  
...  
Keyword(s):  
Bond Activation ◽  
Iridium Complex ◽  
Iridium Complexes ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Metal Ligand

Metal–ligand cooperativity can be used in iridium complexes with an unsymmetrically substituted redox-active diamidobenzene ligand for bond activation reactions.

scholarly journals Si–C(sp3) bond activation through oxidative addition at a Rh(i) centre

2020 ◽  
Vol 49 (17) ◽  
pp. 5416-5419
Author(s):  
S. Azpeitia ◽  
A. J. Martínez-Martínez ◽  
M. A. Garralda ◽  
A. S. Weller ◽  
M. A. Huertos
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Oxidative Addition

Rhodium promoted a fast, quantitative and room temperature Si–CH3 bond activation.

Room temperature phosphorescent triarylborane functionalized iridium complexes

2019 ◽  
Vol 48 (20) ◽  
pp. 6817-6823 ◽  
Author(s):  
George Rajendra Kumar ◽  
Santosh Kumar Behera ◽  
Pakkirisamy Thilagar
Keyword(s):  
Room Temperature ◽  
Iridium Complexes

We report a series of room temperature phosphorescent compounds 1–6 composed of triarylborane (TAB) and cyclometallated iridium complexes.

Room-Temperature C–F Bond Activation of Hexafluorobenzene by a Tailor-Made Pt(0) Intermediate, [(dtbpm)Pt(0)]

1992 ◽  
Vol 125 (3) ◽  
pp. 659-661 ◽  
Author(s):  
Peter Hofmann ◽  
Günter Unfried
Keyword(s):  
Room Temperature ◽  
Bond Activation

Reactions of Olefins with Ruthenium Hydride Nanoparticles: NMR Characterization, Hydride Titration, and Room-Temperature CC Bond Activation

2008 ◽  
Vol 47 (11) ◽  
pp. 2074-2078 ◽  
Author(s):  
Jordi García-Antón ◽  
M. Rosa Axet ◽  
Susanna Jansat ◽  
Karine Philippot ◽  
Bruno Chaudret ◽  
...  
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Ruthenium Hydride ◽  
Nmr Characterization

ChemInform Abstract: Rh-Catalyzed Sequential Oxidative C-H and N-N Bond Activation: Conversion of Azines into Isoquinolines with Air at Room Temperature.

ChemInform ◽  
2014 ◽  
Vol 45 (52) ◽  
pp. no-no
Author(s):  
Wenjia Han ◽  
Guoying Zhang ◽  
Guangxing Li ◽  
Hanmin Huang
Keyword(s):  
Room Temperature ◽  
Bond Activation

Anomalous Efficacy of Bimetallic Au/Pd Nanoclusters in C–Cl Bond Activation and Formal Metathesis-type C–B Bond Activation at Room Temperature

2012 ◽  
Vol 41 (6) ◽  
pp. 630-632 ◽  
Author(s):  
Raghu Nath Dhital ◽  
Hidehiro Sakurai
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Type C

Complicated Electronic Process of C–C σ-Bond Activation of Cyclopropene by Ruthenium and Iridium Complexes: Theoretical Study

2012 ◽  
Vol 31 (23) ◽  
pp. 8189-8199 ◽  
Author(s):  
Atsushi Ishikawa ◽  
Yudai Tanimura ◽  
Yoshihide Nakao ◽  
Hirofumi Sato ◽  
Shigeyoshi Sakaki
Keyword(s):  
Bond Activation ◽  
Theoretical Study ◽  
Iridium Complexes ◽  
Electronic Process
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