A high pressure Raman study on confined individual iodine molecules as molecular probes of structural collapse in the AlPO4-5 framework

2018 ◽  
Vol 20 (41) ◽  
pp. 26117-26125 ◽  
Author(s):  
Shuanglong Chen ◽  
Zhen Yao ◽  
Hang Lv ◽  
Enlai Dong ◽  
Xibao Yang ◽  
...  

The individual iodine molecules in the channels of AlPO4-5 can be regarded as molecular probes to detect its structural collapse.

1994 ◽  
Vol 63 (3) ◽  
pp. 934-940 ◽  
Author(s):  
Wu Youhong ◽  
Mitsukazu Onomichi ◽  
Shigeo Sasaki ◽  
Hiroyasu Shimizu
Keyword(s):  

1981 ◽  
Vol 64 (4) ◽  
pp. 875-883
Author(s):  
Shiv K Soni ◽  
Daniel Van Gelder

Abstract Due to the existence of 2 asymmetric carbon atoms in: the propoxyphene molecule, there are 4 diastereomers: alpha dextro, alpha levo, beta dextro, and beta levo. Only α-d-propoxyphene is included under the federal Controlled Substances Act. Baseline separations of propoxyphene from various incipients (aspirin, caffeine, phenacetin, and acetaminophen) present in pharmaceutical and illicit preparations, and between the alpha and beta diastereomers, were achieved by high pressure liquid chromatography. The column eluant was collected and propoxyphene was extracted. The optical isomers were differentiated and characterized by melting points and by chemical microcrystalline tests. Using hot stage thermomicroscopy, the eutectic melting points of binary isomeric mixtures of propoxyphene bases and salts were found to be depressed about 10° and 15-30°C, respectively, below the individual isomer melting points. The characteristic microcrystals formed with the alpha racemic mixtures by using a glycerin-aqueous gold chloride reagent were not produced by the beta racemic mixtures.


2011 ◽  
Vol 248 (5) ◽  
pp. 1154-1157 ◽  
Author(s):  
Bo Liu ◽  
Bingbing Liu ◽  
Quanjun Li ◽  
Zepeng Li ◽  
Mingguang Yao ◽  
...  

1978 ◽  
Vol 25 (4) ◽  
pp. 209-211 ◽  
Author(s):  
Peter Y. Yu ◽  
Benjamin Welber

1987 ◽  
Vol 87 (6) ◽  
pp. 3587-3590 ◽  
Author(s):  
A. Jayaraman ◽  
G. A. Kourouklis ◽  
R. C. Haddon

2013 ◽  
Vol 03 (01) ◽  
pp. 28-32 ◽  
Author(s):  
Pei-Lun Lee ◽  
Eugene Huang ◽  
Shu-Cheng Yu ◽  
Yen-Hua Chen
Keyword(s):  

2020 ◽  
Vol 124 (49) ◽  
pp. 11189-11196
Author(s):  
Takahiro Takekiyo ◽  
Yoshihiro Koyama ◽  
Kiyoto Matsuishi ◽  
Yukihiro Yoshimura
Keyword(s):  

1995 ◽  
Vol 80 (11-12) ◽  
pp. 1157-1165 ◽  
Author(s):  
Ji-an Xu ◽  
Eugene Huang ◽  
Jung-fu Lin ◽  
Lilian Yunyi Xu

2008 ◽  
Vol 121 (16) ◽  
pp. 162002
Author(s):  
Y Narita ◽  
T Kume ◽  
S Sasaki ◽  
H Shimizu ◽  
S Maekawa ◽  
...  

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