Selective and highly efficient synthesis of xanthenedione or tetraketone derivatives catalyzed by ZnO nanorod-decorated graphene oxide

2018 ◽  
Vol 42 (17) ◽  
pp. 14246-14262 ◽  
Author(s):  
Sepideh Hasanzadeh Banakar ◽  
Mohammad G. Dekamin ◽  
Amene Yaghoubi

A new and efficient method for the pseudo three-component synthesis of diverse tetraketone or xanthenedione derivatives has been described in the presence of ZnO nanorods decorated graphene oxide.

2014 ◽  
Vol 50 (99) ◽  
pp. 15760-15763 ◽  
Author(s):  
Huanhuan Li ◽  
Yang Wang ◽  
Kai Yuan ◽  
Ye Tao ◽  
Runfeng Chen ◽  
...  

The rhodium-catalyzed synthesis of phenazasilines from readily achievable biarylhydrosilanes is presented. This highly efficient method offers opportunities for preparing π-extended phenazasilines with enhanced optoelectronic properties for device applications in organic electronics.


Synlett ◽  
2019 ◽  
Vol 30 (12) ◽  
pp. 1442-1446 ◽  
Author(s):  
Zhang-qi Lin ◽  
Chao-dong Li ◽  
Zi-chun Zhou ◽  
Shuai Xue ◽  
Jian-rong Gao ◽  
...  

A simple and highly efficient method for the preparation of tetrasubstituted NH-pyrrole from a wide range of chalcones and diethyl iminodiacetates via a Cu(OAc)2-promoted oxidation/[3+2]cycloaddition/aromatization cascade reaction has been developed. This reaction proceeds through dehydrogenations, deamination, and oxidative cyclization, affording the corresponding products in good to excellent yields. This convenient methodology for constructing tetrasubstituted NH-pyrroles has several advantages over existing methods, such as the use of easily accessible chalcones and readily available diethyl iminodiacetates, and mild reaction conditions. A wide range of substrates are tolerated.


Synthesis ◽  
2017 ◽  
Vol 49 (16) ◽  
pp. 3643-3653 ◽  
Author(s):  
Qinghan Li ◽  
Zhen Zhang ◽  
Xuebei Shao ◽  
Gang Zhang ◽  
Xinying Li

A simple and mild catalytic SN2′ substitution reaction of propargyl acetates with organoaluminum reagents is reported. The SN2′ substitution reaction of propargyl acetates with organoaluminum reagents mediated by Pd(PhP3)2Cl2 (1 mol%)/PPh3 (2 mol%)/K2CO3 in tetrahydrofuran at 60 °C for 3–4 hours afforded the corresponding multi-substituted allenes in good yields (up to 94%) with high selectivities (up to 99%). The process was simple and easily performed, which offers an efficient method to synthesize the multi-substituted allene derivatives.


2011 ◽  
Vol 8 (4) ◽  
pp. 2016-2019 ◽  
Author(s):  
L. S. Patil ◽  
V. S. Suryawanshi ◽  
O. B. Pawar ◽  
N. D. Shinde

An efficient synthesis of bisphenols is described by condensation of substituted phenols with corresponding cyclic ketones in presence of cetyltrimethylammonium chloride and 3-mercaptopropionic acid as a catalyst in extremely high purity and yields.


2015 ◽  
Vol 3 (34) ◽  
pp. 6871-6876 ◽  
Author(s):  
Chong Zhu ◽  
Siwei Yang ◽  
Gang Wang ◽  
Runwei Mo ◽  
Peng He ◽  
...  

We demonstrated that graphene oxide can be oxidized and cut into graphene quantum dots by hydroxyl radicals which is obtained by catalytic decomposition of hydrogen peroxide with a tungsten oxide nanowire catalyst.


RSC Advances ◽  
2015 ◽  
Vol 5 (114) ◽  
pp. 94222-94226 ◽  
Author(s):  
Giwoong Nam ◽  
Jae-Young Leem

We used a hydrothermal method combined with a graphene oxide (GO)/ZnO seed layer to fabricate a ZnO nanorod based fast-response UV detector.


2017 ◽  
Vol 19 (4) ◽  
pp. 1102-1108 ◽  
Author(s):  
Chunqing Lou ◽  
Ning Zhu ◽  
Ronghua Fan ◽  
Hailong Hong ◽  
Limin Han ◽  
...  

A convenient and efficient method for the synthesis of 2-mercaptobenzothiazoles from disulfide and CS2 was performed by dynamic interchange reaction between a disulfide and a metal sulfide in water.


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