Ultrafine bimetallic Pt–Ni nanoparticles immobilized on 3-dimensional N-doped graphene networks: a highly efficient catalyst for dehydrogenation of hydrous hydrazine

2019 ◽  
Vol 7 (1) ◽  
pp. 112-115 ◽  
Author(s):  
Amit Kumar ◽  
Xinchun Yang ◽  
Qiang Xu

Ultrafine and uniformly dispersed bimetallic Pt–Ni nanoparticles (NPs) have been immobilized on novel 3-dimensional N-doped graphene networks (NGNs) by a facile wet chemical reduction method, which exhibit extremely high catalytic activity for the dehydrogenation of hydrazine hydrate.

2014 ◽  
Vol 2 (12) ◽  
pp. 4384-4390 ◽  
Author(s):  
Jing-Jing Lv ◽  
Jie-Ning Zheng ◽  
Shan-Shan Li ◽  
Li-Li Chen ◽  
Ai-Jun Wang ◽  
...  

Porous Pt–Pd nanodendrites were fabricated by a co-chemical reduction method using both PVP and urea as the co-stabilizing and co-structure-directing agents. The Pt–Pd nanodendrites displayed high catalytic activity and stability toward the electrooxidation of methanol and ethylene glycol in alkaline media.


2020 ◽  
Vol 23 ◽  
pp. 720-725 ◽  
Author(s):  
P. Srimara ◽  
T. Chevapruk ◽  
P. Kumnorkaew ◽  
T. Muangnapoh ◽  
P. Vas-Umnuay

2020 ◽  
Vol 20 (3) ◽  
pp. 1723-1731 ◽  
Author(s):  
Lang Qiu ◽  
Hengbo Yin ◽  
Aili Wang ◽  
Lingqin Shen ◽  
Wei Tao

Hydroxyapatite nanorod-supported metallic Cu0 nanoparticle catalysts (Cux/HAP) were prepared by the wetness chemical reduction method. The metallic Cu0 nanoparticles were well dispersed on the surfaces of the HAP nanorods. The alkaline HAP nanorods inhibited the crystal growth of the metallic Cu0 nanoparticles. The HAP nanorods also retarded the oxidation of the metallic Cu0 nanoparticles. The Cux/HAP catalyst exhibited a higher catalytic activity for the oxidation of 1,2-propanediol with gaseous oxygen to lactic, acetic, and formic acids with the total selectivity of 70.3% even at a lower reaction temperature of 140 °C. The total selectivity of lactic, acetic, and formic acids reached 93.1% at a mild reaction temperature of 180 °C. However, the sole monometallic Cu0 nanoparticles or HAP nanorods had no catalytic activity for the oxidation of 1,2-propanediol. The metallic Cu0 nanoparticles and alkaline HAP nanorods in the Cux/HAP catalyst synergistically catalyzed the oxidation of 1,2-propanediol to carboxylic acid.


2011 ◽  
Vol 18 (3) ◽  
pp. 244-249 ◽  
Author(s):  
Hyun-Seon Hong ◽  
Young-Dae Ko ◽  
Lee-Seung Kang ◽  
Geon-Hong Kim ◽  
Hang-Chul Jung

2015 ◽  
Vol 778 ◽  
pp. 144-147
Author(s):  
Si Qin Deligen ◽  
Bao Agula

The mesoporous CeO2were prepared via a surfactant-assisted method of nanoparticle assembly, CTAB was used as surfactant. The mesoporous CeO2were used as the supports for preparingxAu/CeO2catalysts by the chemical reduction method, and the catalytic activities of the total oxidation of propane were studied. The prepared catalysts were characterized by XRD, TEM and N2adsorption techniques. The content of Au can affect the catalytic properties of thexAu/CeO2catalysts. 4Au/CeO2exhibited the highest catalytic activity in propane complete oxidation with theT100of 420 °C.


2016 ◽  
Vol 16 (3) ◽  
pp. 810-816
Author(s):  
Rong Cheng ◽  
Can Cheng ◽  
Peng Liu ◽  
Lei Shi ◽  
Zhong Ma

Chlorinated phenols are a kind of environmental priority pollutant that attract much attention. Nanosized Fe and Fe/Ni materials are considered as promising options for chlorinated phenol removal. The effect of Ni morphology on the removal of pentachlorophenol (PCP) with Fe/Ni nanomaterials was investigated in this study. Iron nanoparticles and nickel nanomaterials with different shapes were synthesized using a chemical reduction method and wet chemical techniques, respectively. The concentrations of PCP and chloride in solutions were measured with and without Ni present. The intermediates of PCP were also analyzed. The results showed that the dechlorination of PCP was promoted by Ni nanomaterials, among which the tubular porous Ni nanomaterials expressed the most promotion, then those with net shape and nanochains. However, the tubular porous Ni nanomaterials inhibited the removal of PCP, and the other two expressed a certain promotion. In the Fe/Ni system, Fe nanoparticles transformed into magnetite (Fe3O4) and/or maghemite (Fe2O3), and Ni nanomaterials were still pure Ni after reaction. The introduction of Ni nanomaterials would improve dechlorination of PCP, but the removal of PCP might be inhibited or improved as the morphology of Ni changed.


Author(s):  
Kamyar Shameli ◽  
Majid Darroudi ◽  
Mansor Bin Ahmad ◽  
Wan Md. Zin Wan Yunis ◽  
Nor Azowa Ibrahim

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