A heterogeneous single Cu catalyst of Cu atoms confined in the spinel lattice of MgAl2O4 with good catalytic activity and stability for NO reduction by CO

2019 ◽  
Vol 7 (12) ◽  
pp. 7202-7212 ◽  
Author(s):  
Jichun Wu ◽  
Yuanzhi Li ◽  
Yi Yang ◽  
Qian Zhang ◽  
Li Yun ◽  
...  

A heterogeneous single Cu catalyst exhibits good catalytic activity and durability at high temperature for NO reduction by CO due to the confinement effect of spinel lattice.

RSC Advances ◽  
2018 ◽  
Vol 8 (39) ◽  
pp. 21699-21711
Author(s):  
Yu Huanhuan ◽  
Chen Fayun ◽  
Zhubaolin Zhubaolin ◽  
Huang Weiping ◽  
Zhang Shoumin

A CePO4–GdPO4 composite was prepared by a general ultrasound method and could be a good support for gold nanocatalysts. Au/CePO4–GdPO4 catalysts with a low content of gold showed good catalytic activity, high temperature resistance and stability for CO oxidation.


Author(s):  
Bei-Jing Zhong ◽  
Hao Tang

The reduction of NO over coal-derived chars and the catalytic effect of Fe on NO-char reaction during char combustion were investigated in a drop-tube furnace in a temperature range of 1323-1523K. The catalytic characteristics of Fe in the NO–char reaction were studied in detail. The results show that iron (Fe) is an effective catalyst for the NO reduction by char derived from de-ashed coal at a high temperature, i.e., the chars with catalysts have high activity in the NO-char reaction. Furthermore, the stoichiometric ratio (SR) in the reaction zone has a significant influence on the catalytic activity of Fe-catalysts, which will be more effective in SR=0.7-0.9. The catalytic activity of Fe depends slightly on its loading amount, while the specific activity of the catalyst obviously decreased with the increasing of the Fe-loading amount. The effect of the temperatures used in the experiments on the NO reduction is small, which suggests the NO-char reaction mainly depends on the diffusion of reactants to char, the reactants' surface adsorption, and the desorption of products under high temperature. However, the effect of the temperature on NO reduction by metal-free char is much more important than that of NO reduction by Fe-loaded char.


2020 ◽  
Vol 10 (8) ◽  
pp. 2359-2368 ◽  
Author(s):  
Shuhao Zhang ◽  
Jaeha Lee ◽  
Do Heui Kim ◽  
Taejin Kim

The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.


2019 ◽  
Vol 43 (47) ◽  
pp. 18611-18618 ◽  
Author(s):  
Xiaoran Niu ◽  
Zuotao Lei ◽  
Chunhui Yang

The effectiveness of the tandem catalysts was verified by a combination of Co98Ce2 for low temperature reactions and Co15Ce85 for high temperature reactions.


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