A safe, convenient liquid phase pre-sodiation method for titanium-based SIB materials

2019 ◽  
Vol 55 (98) ◽  
pp. 14761-14764 ◽  
Author(s):  
Yang Cao ◽  
Tianqi Zhang ◽  
Xingguo Zhong ◽  
Tianyou Zhai ◽  
Huiqiao Li

We develop a pre-sodiation method by simply immersing the electrode in a liquid sodium source to reduce irreversible capacity loss for titanium-based materials.

2016 ◽  
Vol 4 (47) ◽  
pp. 18416-18425 ◽  
Author(s):  
Fu-Da Yu ◽  
Lan-Fang Que ◽  
Zhen-Bo Wang ◽  
Yin Zhang ◽  
Yuan Xue ◽  
...  

We report an effective approach to fabricate layered-spinel capped nanotube assembled 3D Li-rich hierarchitectures as a cathode material for Li-ion batteries. The resultant material exhibits a reduced first-cycle irreversible capacity loss, rapid Li-ion diffusion rate and excellent cycle stability.


2020 ◽  
Vol 8 (44) ◽  
pp. 23368-23375
Author(s):  
Shahid Mirza ◽  
Zihan Song ◽  
Hongzhang Zhang ◽  
Arshad Hussain ◽  
Huamin Zhang ◽  
...  

A pre-sodiation strategy of using Na4V2(PO4)3 cathode to compensate the irreversible capacity loss of hard carbon anode is demonstrated and improves the energy density of sodium ion batteries.


2000 ◽  
Vol 147 (6) ◽  
pp. 2110 ◽  
Author(s):  
Karim Zaghib ◽  
Gabrielle Nadeau ◽  
Kimio Kinoshita

1999 ◽  
Author(s):  
W. Jiang ◽  
X. Song ◽  
K. Kinoshita ◽  
T. Tran

2019 ◽  
Vol 7 (19) ◽  
pp. 11996-12007 ◽  
Author(s):  
Julija Vinckevičiūtė ◽  
Maxwell D. Radin ◽  
Nicholas V. Faenza ◽  
Glenn G. Amatucci ◽  
Anton Van der Ven

Interlayer cation migration in layered cathodes, which can lead to irreversible capacity loss, is affected by surrounding transition metals.


2007 ◽  
Vol 124-126 ◽  
pp. 995-998
Author(s):  
Joong Pyo Shim ◽  
Hong Ki Lee ◽  
Byung Ho Song

Natural graphite anodes were treated by different methods to improve their cyclability. We tried following methods; heat-treatment at 550oC for graphite powder, addition of carbon black for electrode and VC (vinylene carbonate) in electrolyte. All methods decreased capacity fade rate during constant cycling. The addition of carbon black decreased capacity fade significantly but increased irreversible capacity much at first cycle. Heat-treatment and VC were also effective for cycling and irreversible capacity loss.


2012 ◽  
Vol 512-515 ◽  
pp. 1409-1412
Author(s):  
Yu Qing Qiao ◽  
Min Shou Zhao ◽  
Li Min Wang

Microstructure and self-discharge characteristics of Ti-Zr-V-Cr-Ni-Ce hydrogen storage electrode have been investigated by XRD, FESEM-EDS and EIS measurements. Self-discharge properties indicate that the irreversible capacity loss is negative, which is different from that of AB5 alloy electrode. The capacity loss can be divided in two parts, one is due to the deterioration of the hydrogen storage alloy, which will result in the decrease of discharge capacity, and the other is due to the continually activated, which will result in the increase of discharge capacity.


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