Rational synthesis, crystal structure, and sensing and adsorption properties of luminescent metal–organic frameworks

CrystEngComm ◽  
2019 ◽  
Vol 21 (33) ◽  
pp. 4880-4897 ◽  
Author(s):  
Chuanbin Fan ◽  
Ziao Zong ◽  
Xiangmin Meng ◽  
Xia Zhang ◽  
Xiaoyin Zhang ◽  
...  

Five novel Cd(ii) metal–organic frameworks (Cd-MOFs) were synthesized employing a rational design approach under solvothermal conditions. The luminescence sensing and the targeted dye adsorption properties of the MOFs 1–5 are investigated.

CrystEngComm ◽  
2018 ◽  
Vol 20 (34) ◽  
pp. 4973-4988 ◽  
Author(s):  
Chuanbin Fan ◽  
Ziao Zong ◽  
Xia Zhang ◽  
Cungang Xu ◽  
Zheng Zhu ◽  
...  

Four novel Co(ii) metal–organic frameworks were synthesized employing a rational design approach under solvothermal conditions.


2015 ◽  
Vol 44 (9) ◽  
pp. 4238-4245 ◽  
Author(s):  
Chuan-Lei Zhang ◽  
Ling Qin ◽  
Zhen-Zhen Shi ◽  
He-Gen Zheng

Diverse structures of metal–organic frameworks induced by different metal ions under solvothermal conditions exhibit different topological characteristics and spectral properties.


2020 ◽  
Vol 49 (41) ◽  
pp. 14690-14705
Author(s):  
M. Naqi Ahamad ◽  
M. Shahnawaz Khan ◽  
M. Shahid ◽  
Musheer Ahmad

Elaborating the role of uncoordinated carboxylic acid functions in MOFs in post synthetic modification (PSM) through metal capture and hence in tuning dye adsorption properties.


2018 ◽  
Vol 47 (3) ◽  
pp. 716-725 ◽  
Author(s):  
Fengli Chen ◽  
Dongjie Bai ◽  
Yao Wang ◽  
Minghui He ◽  
Xiaoxia Gao ◽  
...  

A pair of polymorphous MOFs derived from a bent diisophthalate ligand were synthesized by modulating solvothermal conditions, exhibiting comparable gas adsorption properties with respect to C2H2, CO2 and CH4.


CrystEngComm ◽  
2019 ◽  
Vol 21 (35) ◽  
pp. 5299-5309 ◽  
Author(s):  
Khushboo Iman ◽  
M. Shahid ◽  
M. Shahnawaz Khan ◽  
Musheer Ahmad ◽  
Farasha Sama

Two new MOFs (CuMOF-1 and CoMOF-2) are synthesized, characterized by spectral and magnetic studies and employed for selective dye adsorption properties.


2016 ◽  
Vol 52 (4) ◽  
pp. 717-720 ◽  
Author(s):  
Meihui Wang ◽  
Hao Yang ◽  
Xianlong Zhou ◽  
Wei Shi ◽  
Zhen Zhou ◽  
...  

Utilizing the adsorption properties of metal–organic-frameworks to prepare a well-dispersed nano-SnO2@porous-carbon LIB anode material with superior capacity and cycle stability.


CrystEngComm ◽  
2015 ◽  
Vol 17 (27) ◽  
pp. 4992-5001 ◽  
Author(s):  
Aurel Tăbăcaru ◽  
Simona Galli ◽  
Claudio Pettinari ◽  
Norberto Masciocchi ◽  
Thomas M. McDonald ◽  
...  

The synthesis, thermal behavior, crystal structure and adsorption properties of two novel MOFs isolated by coupling Ni(ii) and Cu(ii) to the extended tris(pyrazolate) strut 1,3,5-tris((1H-pyrazol-4-yl)phenyl)benzene are reported.


2020 ◽  
Vol 75 (8) ◽  
pp. 727-732
Author(s):  
Chen Zhang ◽  
Jian-Qing Tao

AbstractA new Cu(II) metal-organic framework, [Cu(L)(OBA)·H2O]n (1) [H2OBA = 4,4′-oxybis(benzoic acid), L = 3,5-di(1H-benzimidazol-1-yl)pyridine] was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis and single-crystal X-ray diffraction. Complex 1 is a four-connected uni-nodal 2D net with a (44·62) topology which shows an emission centered at λ ∼393 nm upon excitation at λ = 245 nm. Moreover, complex 1 possesses high photocatalytic activities for the decomposition of Rhodamine B (RhB) under UV light irradiation.


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