Sulfide-Based Photocatalysts Using Visible Light, with Special Focus on In2S3, SnS2 and ZnIn2S4

Sulfides are frequently used as photocatalysts, since they absorb visible light better than many oxides. They have the disadvantage of being more easily photocorroded. This occurs mostly in oxidizing conditions; therefore, they are commonly used instead in reduction processes, such as CO2 reduction to fuels or H2 production. Here a summary will be presented of a number of sulfides used in several photocatalytic processes; where appropriate, some recent reviews will be presented of their behaviour. Results obtained in recent years by our group using some octahedral sulfides will be shown, showing how to determine their wavelength-dependent photocatalytic activities, checking their mechanisms in some cases, and verifying how they can be modified to extend their wavelength range of activity. It will be shown here as well how using photocatalytic or photoelectrochemical setups, by combining some enzymes with these sulfides, allows achieving the photo-splitting of water into H2 and O2, thus constituting a scheme of artificial photosynthesis.

Photocatalytic Degradation of Methylene Blue and Metanil Yellow Dyes Using Green Synthesized Zinc Oxide (ZnO) Nanocrystals

In this work, ZnO nanocrystals (NCs) have been effectively synthesized by a simple, efficient and cost-effective method using coconut husk extract as a novel fuel. The synthesized NCs are characterized by UV-Vis, XRD, FT-IR, SEM, EDX, Raman and PL studies. The obtained ZnO were found to be UV-active with a bandgap of 2.93 eV. The X-ray diffraction pattern confirms the crystallinity of the ZnO with hexagonally structured ZnO with a crystallite size of 48 nm, while the SEM analysis reveals the hexagonal bipyramid morphology. Photocatalytic activities of the synthesized ZnO NCs are used to degrade methylene blue and metanil yellow dyes.

Correction: Zgura et al. Cytotoxicity, Antioxidant, Antibacterial, and Photocatalytic Activities of ZnO–CdS Powders. Materials 2020, 13, 182

In the original publication [...]